High temperature enthalpy increments and thermodynamic functions of ZrCo: An experimental and theoretical study

Chattaraj D.; Jat Ram Avtar; Parida S. C.; Agarwal Renu; Dash Smruti

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High temperature enthalpy increments and thermodynamic functions of ZrCo: An experimental and theoretical study

机译：ZrCo的高温焓增量和热力学函数：实验和理论研究

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The thermodynamic properties of ZrCo intermetallic were investigated both experimentally and theoretically to determine its applicability for the storage of hydrogen isotopes. The enthalpy increments of ZrCo were measured using a high temperature inverse drop calorimeter in the temperature range 642-1497 K. The enthalpy increments and heat capacity obtained for Zr0.5Co0.5(s) in the temperature range 642-1497K were fitted into following polynomial expressions:

机译：通过实验和理论研究了ZrCo金属间化合物的热力学性质，以确定其在氢同位素存储中的适用性。使用高温逆滴热量计在642-1497 K的温度范围内测量ZrCo的焓增量。将Zr0.5Co0.5在642-1497K的温度范围内获得的焓增量和热容量拟合如下：多项式表达式：

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来源
《Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems》 |2015年第null期|共5页
作者
Chattaraj D.; Jat Ram Avtar; Parida S. C.; Agarwal Renu; Dash Smruti;
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原文格式 PDF
正文语种 eng
中图分类其他物理及物理化学分析法;热化学;
关键词
Tritium storage; ZrCo alloy; Inverse drop calorimeter; Enthalpy increment; Thermodynamic functions; Ab-initio study;

机译：storage存储;ZrCo合金;反滴热仪;焓增量;热力学函数;Ab-initial研究;

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机译：ZrCo的高温焓增量和热力学函数：实验和理论研究
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High temperature enthalpy increments and thermodynamic functions of ZrCo: An experimental and theoretical study

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