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Thermal behavior of extracted and delignified pine wood flour

机译:提取和脱木质松木粉的热行为

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摘要

To investigate the effect of extractives and lignin on the thermal stability of wood flour (WF), thermogravimetric analysis was used to determine thermal degradation behavior of extracted and delignified mixed pine WF. The contribution of lignin to thermal stability was greater than that of extractives. Removing extractives resulted in improved thermal stability by increasing onset temperature T_0, and solvents with greater polarity contributed more to increasing T_0. However, solvent extraction had less effect on decomposition temperature (T_2) than did delignification, which significantly decreased T_2. A shoulder peak was observed only in delignified WF. Acetone/water extraction, hot-water extraction, and delignification are all significant model terms for variation in T_0; delignification is the most significant factor affecting T_0 and T_2.
机译:为了研究提取物和木质素对木粉(WF)热稳定性的影响,使用热重分析法确定提取和脱木质素的混合松木WF的热降解行为。木质素对热稳定性的贡献大于提取物。去除萃取物可通过提高起始温度T_0来提高热稳定性,而极性更大的溶剂则更多地有助于提高T_0。但是,溶剂萃取对分解温度(T_2)的影响小于去木质素,这显着降低了T_2。仅在脱木质素的WF中观察到肩峰。丙酮/水提取,热水提取和去木质素作用都是T_0变异的重要模型项。去木质素是影响T_0和T_2的最重要因素。

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