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Infrared spectroscopy of SO2 clusters in rare gas matrices revisited: Assignment of species in Ar matrix

机译:红外光谱在稀有气体基质中的SO2团簇的再探讨:Ar矩阵中的物种分配

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摘要

We have observed infrared spectra of the SO2 clusters in rare gas matrices (Ar,Kr,Xe). The spectral dependence on temperature and concentration led us to the firm assignment of the SO2 dinner in Kr and Xe, the result of which was used to reassign dimeric vibrational transitions in Ar that have been controversial for more than ten years.
机译:我们已经观察到稀有气体基质(Ar,Kr,Xe)中SO2团簇的红外光谱。光谱对温度和浓度的依赖性使我们确定了Kr和Xe中SO2晚餐的牢固分配,其结果被用于重新分配Ar的二聚振动跃迁,该跃迁已经引起了十多年的争议。

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