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Low-Temperature Paramagnetism of AlCuFe Quasicrystals

机译:AlCuFe准晶体的低温顺磁性

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The magnetic properties of the Al_(62)Cu_(25.5)Fe_(12.5) alloy in different structural states (from as-quenched disordered state to single-phase quasicrystalline state) that were obtained by various heat treatments have been studied. The concentrations of magnetically active-paramagnetic and magnetically ordered-iron atoms were determined from the Curie constant (C_(CW)) and spontaneous magnetization (I_S) curves, respectively. The Curie constant was determined from the temperature dependences of the magnetic susceptibility that follows the Curie-Weiss law. It was shown that changes in the concentration of iron atoms correlate with changes in the residual electrical conductivity sigma_0, which is determined by the concentration of free charge carriers. The strong dependence of the low-temperature paramagnetism of the Al-Cu-Fe alloys on the lattice perfection is due to the fact that the unpaired spins of iron atoms are formed only in the presence of local lattice distortions of the icosahedral phase.
机译:研究了通过各种热处理获得的Al_(62)Cu_(25.5)Fe_(12.5)合金在不同结构态(从淬火无序态到单相准晶态)的磁性能。分别从居里常数(C_(CW))和自发磁化(I_S)曲线确定磁活性-顺磁和铁有序铁原子的浓度。居里常数由遵循居里-魏斯定律的磁化率的温度依赖性确定。结果表明,铁原子浓度的变化与残余电导率sigma_0的变化相关,后者由自由电荷载流子的浓度决定。 Al-Cu-Fe合金的低温顺磁性对晶格完善性的强烈依赖性是由于这样的事实,即仅在存在二十面体相的局部晶格畸变的情况下才形成铁原子的不成对自旋。

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