Electron-Accepting Conjugated Materials Based on 2-Vinyl-4,5-dicyanoimidazoles for Application in Organic Electronics

摘要

We report the Heck coupling of 2-vinyl-4,5-dicyanoimidazole (vinazene) with selected di- and trihaloaromatics in an effort to prepare linear and branched electron-accepting conjugated materials for applicationin organic electronics. By selecting the suitable halo-aromatic moiety, it is possible to tune theHOMO-LUMO energy levels, absorption, and emission properties for a specific application. In thisregard, materials with strong photoluminescence from blue → green → red are reported that may havepotential application in organic light-emitting diodes (OLEDs). Furthermore, derivatives with strongabsorption in the visible spectrum, coupled with favorable HOMO-LUMO levels, have been used toprepare promising organic photovoltaic devices (OPVs) when combined with commercially availablesemiconducting donor polymers.