Synthesis of bisquinolone-based mono- and diphosphine ligands of the aza-BINAP type

Arshad N; Hashim J; Kappe CO

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Synthesis of bisquinolone-based mono- and diphosphine ligands of the aza-BINAP type

机译：基于双喹诺酮的aza-BINAP型单膦和二膦配体的合成

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摘要

Mono- and bisphosphine ligands based on the 4,4'-bisquinolone structural framework (BIQUIP ligands) were generated by direct microwave-assisted palladium-catalyzed carbon-phosphorus cross-coupling reactions employing the corresponding heteroaryl bromides and diphenylphosphine as substrates.

机译：基于4,4'-双喹诺酮结构框架的单-和双膦配体（BIQUIP配体）是通过直接微波辅助的钯催化的碳-磷交叉偶联反应生成的，采用相应的杂芳基溴化物和二苯基膦作为底物。

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《The Journal of Organic Chemistry》 |2008年第12期|共4页
作者
Arshad N; Hashim J; Kappe CO;
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正文语种 eng
中图分类有机化学;
关键词
CHIRAL METAL-COMPLEXES; CATALYZED STEREOSELECTIVE REACTIONS; CROSS-COUPLING REACTIONS; ASYMMETRIC REACTIONS; ENANTIOSELECTIVE SYNTHESIS; SYMMETRICAL BISQUINOLONES; ACID-DERIVATIVES; RHODIUM COMPLEX; BINOL; HYDROGENATIONS;

机译：手性金属络合物;催化的立体选择性反应;交叉偶联反应;不对称反应;对映选择性合成;对称双对苯二酚;酸衍生物;铑络合物;二元醇;加氢反应;

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1. Synthesis of bisquinolone-based mono- and diphosphine ligands of the aza-BINAP type [J] . Arshad N, Hashim J, Kappe CO The Journal of Organic Chemistry . 2008,第12期

机译：基于双喹诺酮的aza-BINAP型单膦和二膦配体的合成
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5. Synthesis of gold complexes from diphosphine ligands and screening reactions of heterocyclic acetylacetonato (ACAC) ligands with transitional metal complexes. [D] . Nyamwihura, Rogers. 2015

机译：由二膦配体合成金配合物，以及杂环乙酰丙酮基（ACAC）配体与过渡金属配合物的筛选反应。
6. Asymmetric Catalysis Special Feature Part II: Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation [O] . Liqin Qiu, Jing Wu, Shusun Chan, 2004

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机译：陀螺仪（如轿厢内）在笼内的Cl Pt Cl旋转器等复合物的单声道和无用的反应，如二均二膦配体

Synthesis of bisquinolone-based mono- and diphosphine ligands of the aza-BINAP type

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