Iodine-mediated highly regio- and stereoselective iodoamination of ferrocenyl allene: An approach for the synthesis of ferrocene-containing allylic amines

摘要

A straightforward and efficient protocol for the highly regio- and stereoselective synthesis of ferrocene-containing allylic amine derivatives via an iodine-mediated iodoamination of ferrocenyl allene was developed. The regio- and stereoselectivity of this reaction may be controlled by the steric effect of the bulky ferrocene group.