Synthesis, characterization, and reaction of a ketone-derived 1,4-dienolate compound

Kagan G.; Li W.; Sun C.; Hopson R.; Williard P.G.

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Synthesis, characterization, and reaction of a ketone-derived 1,4-dienolate compound

机译：酮类1,4-二烯酸酯化合物的合成，表征和反应

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The tetrahydrofuran tetrasolvated dimeric lithium dienolate derived from 2,2,7,7-tetramethyloctan-3,6-dione is characterized in the solid state by X-ray diffraction analysis and in solution by diffusion NMR. This dienolate was reacted with tropanone to yield two new products that are also described.

机译：衍生自2,2,7,7-四甲基辛烷-3,6-二酮的四氢呋喃四溶剂化的二烯基二烯酸锂通过X射线衍射分析表征为固态，并通过扩散NMR表征为溶液。使该二烯酸酯与托帕酮反应以产生两种也描述的新产物。

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《The Journal of Organic Chemistry》 |2011年第1期|共6页
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Kagan G.; Li W.; Sun C.; Hopson R.; Williard P.G.;
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正文语种 eng
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Synthesis, characterization, and reaction of a ketone-derived 1,4-dienolate compound

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