首页>
外文期刊>The Journal of Organic Chemistry
>Examples of regioselective anion recognition among a family of two-, three-, and four-'armed' bis-, tris-, and tetrakis(thioureido) [n]polynorbornane hosts
【24h】
Examples of regioselective anion recognition among a family of two-, three-, and four-'armed' bis-, tris-, and tetrakis(thioureido) [n]polynorbornane hosts
A family of conformationally preorganized, [n]polynorbornane-based anion hosts 1a,b-6a,b have been synthesized. The series includes receptors with 4, 8, and 12 H-bond donors. Using ~1H NMR titration techniques, evaluation of the new hosts against a series of alkyl and aryl dicarboxylates as well as a range of phosphoanionic species has revealed that the tris(thioureido) hosts (in particular 3a) are capable of regioselectively binding dicarboxylates and pyrophosphate (H _2PPi ~(2-)).
展开▼