Study of surface-bulk mass transport and phase transformation in nano-TiO_2 using hyperfine interaction technique

摘要

Phase transition from anatase to rutile for the 70 nm TiO_2 crystallite has been investigated by the time differential perturbed angular correlation (TDPAC) technique. The study involved the annealing of the TiO _2 nanocrystals, adsorbed with the nuclear probe (~(181)Hf/ ~(181)Ta) at trace level, at different temperatures for different durations. The TDPAC measurement was also supported by XRD measurement where the width of the peaks increases with the increase in annealing temperature indicating a crystal growth. The samples annealed up to 823 K for 4 h showed no phase transition, except for the growth of the crystallites. However, it showed phase transition at the same temperature (823 K), when annealed for longer duration, indicating the slower kinetics of the phase transition process. Further the sample, when annealed at 1123 K for 4 h, showed phase transition. It has also been observed that the ~(181)Hf tracer, adsorbed on 70 nm anatase TiO_2, diffuses from surface to bulk during the phase transition process and the extent of diffusion in anatase differs from that in rutile phase. However, surface to bulk mass-transfer is found to play a significant role in the phase transition process.