Synthesis of 20S-protopanaxadiol 20-O-beta-D-glucopyranoside, a metabolite of Panax ginseng glycosides, and compounds related to it

Atopkina LN; Denisenko VA

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Synthesis of 20S-protopanaxadiol 20-O-beta-D-glucopyranoside, a metabolite of Panax ginseng glycosides, and compounds related to it

机译：20S-原人参二醇20-O-β-D-吡喃葡萄糖苷，人参糖代谢产物及其相关化合物的合成

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A preparative semi-synthetic method was developed to prepare 20S-protopanaxadiol 20-O-beta-D-glucopyranoside (1), a metabolite of Panax ginseng glycosides. The 20-O-beta-D-glucopyranosides of 20S-hydroxydammar-24-en-3,12-dione, 3 beta,20S-dihydroxydammar-24-en-12-one, and 3 beta,12 alpha,20S-trihydroxydammar-24-ene were synthesized for the first time.

机译：开发了一种制备半合成方法来制备20S-原人参二醇20-O-β-D-吡喃葡萄糖苷（1），人参糖苷的代谢产物。 20S-hydroxydammar-24-en-3,12-dione，3 beta，20S-dihydroxydammar-24-en-12-one和3 beta，12 alpha，20S-trihydroxydammar的20-O-β-D-吡喃葡萄糖苷首次合成-24-烯。

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来源
《Chemistry of Natural Compounds 》 |2006年第4期| 共7页
作者
Atopkina LN; Denisenko VA;
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正文语种 eng
中图分类化学 ;
关键词
dammarane triterpenoids; glycosylation; Betula; Panax ginseng C. A. Meyer; 20S-protopanaxadiol 20-O-beta-D-glucopyranoside; 20S-hydroxydammar-24-en-3; 12-dione 20-O-beta-D-glucopyranoside; 3 beta; 20S-dihydroxydammar-24-en-12-one 20-O-beta-D-glucopyranoside; 3 beta; 12 alpha; 20S-trihydroxydammar-24-ene 20-O-beta-D-glucopyranoside; INTESTINAL BACTERIAL METABOLITE; SAPONIN METABOLITE; SEMISYNTHETIC ANALOGS; CELLS; APOPTOSIS; GINSENOSIDES; ACTIVATION;

机译：达玛烷三萜;糖基化;桦树;人参CA Meyer;20S-原戊二醇20-O-β-D-吡喃葡萄糖苷;20S-羟基达玛24-en-3;12-二酮20-O-β-D-吡喃葡萄糖苷;3β;20S-dihydroxydammar-24-en-12-one 20-O-beta-D-pyramyranoside;3 beta;12 alpha;20S-trihydroxydammar-24-ene 20-O-beta-D-glucopyranoside;肠溶代谢产物;SAPONIN代谢产物;合成模拟物;细胞;凋亡;人参皂甙;活化;

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1. Synthesis of 20S-protopanaxadiol 20-O-beta-D-glucopyranoside, a metabolite of Panax ginseng glycosides, and compounds related to it [J] . Atopkina LN, Denisenko VA Chemistry of Natural Compounds . 2006 ,第4期

机译：20S-原人参二醇20-O-β-D-吡喃葡萄糖苷，人参糖代谢产物及其相关化合物的合成
2. The skin protective effects of compound K, a metabolite of ginsenoside Rb1 from Panax ginseng [J] . Eunji Kim, Donghyun Kim, Sulgi Yoo, Journal of Ginseng Research . 2018 ,第2期

机译：人参中人参皂苷Rb1代谢物化合物K的皮肤保护作用
3. Production of antioxidant compounds by culture of Panax ginseng CA Meyer hairy roots I. Enhanced production of secondary metabolite in hairy root cultures by elicitation [J] . Jeong GT, Park DH, Ryu HW, Applied biochemistry and biotechnology, Part A. enzyme engineering and biotechnology . 2005 ,第0期

机译：人参CA迈耶毛状根的培养产生抗氧化剂化合物I.诱导引起毛状根培养物中次生代谢产物的产生
4. Enhancement of ginsenoside compounds by far infrared irradiation in ultra fine powdered red ginseng(Panax ginseng C.A. Meyer) [C] . Cheng Wu Jin, Ghimeray Amal Kumar, Won Woo Kim, 2012 12th IEEE International Conference on Nanotechnology. . 2012

机译：在超细粉红色人参中通过远红外辐射增强人参皂甙化合物（Panax ginseng C.A. Meyer）
5. The effect of root parts of Korean Red ginseng (Panax ginseng C.A. Meyer) and alcohol extracts of American ginseng (Panax quinquefolius L.) and Korean Red ginseng on glycemic parameters. [D] . De Souza, Leanne R. 2008

机译：高丽红参（Panax ginseng C.A. Meyer）的根部以及西洋参（Panax quinquefolius L.）和高丽红参的酒精提取物对血糖参数的影响。
6. The skin protective effects of compound K a metabolite of ginsenoside Rb1 from Panax ginseng [O] . Eunji Kim, Donghyun Kim, Sulgi Yoo, 2018

机译：人参中人参皂甙Rb1代谢物化合物K的皮肤保护作用
7. Factors influencing cultivated ginseng (Panax ginseng C. A. Meyer) bioactive compounds [O] . Han Yu, Jiaxin Zhao, Jian You, 2019

机译：影响人参栽培因素（Panax人参C.A. Meyer）生物活性化合物

Synthesis of 20S-protopanaxadiol 20-O-beta-D-glucopyranoside, a metabolite of Panax ginseng glycosides, and compounds related to it

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