K- and Si-rich glasses in harzburgite from Damaping, north China

摘要

A study of potassium- and silica-rich glass (SiO2 = 65.3-67.4%, K2O = 7.1-9.8%, Na2O = 4.4-6.5%) in spongy clinopyroxene rims from anhydrous spinel harzburgite, collected from Damaping (Hannuoba, north China), is reported here. The corroded surface of clinopyroxene along with clear chemical zonation (homogeneous core and partially melted rim) suggests that incongruent melting of primary clinopyroxene is responsible for generating the Si-rich glass in clinopyroxene rims. The degree of clinopyroxene melting is estimated to be higher than 15%. In order to generate glass with K2O contents of 7.0 to 9.8% by clinopyroxene melting at a degree of 15% in a closed system, K2O contents in the primary clinopyroxene should be greater than 1.0 wt%, suggesting a very deep origin for the Damaping harzburgite.