Modelling transannular cyclization of 1(10)E,4E-germacranolide costunolide into eudesmane derivatives

B.B.Khasenov; K.M.Turdybekov

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Modelling transannular cyclization of 1(10)E,4E-germacranolide costunolide into eudesmane derivatives

机译：将1（10）E，4E- Germacranolide costunolide转化为Eudesmane衍生物的环空环化模型

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Semi-empirical quantum-chemical methods were used to model transannular cyclization of 1(10)E, 4E-germacranolide costunolide into eudesmanolides. The confornational states favorable for the transformation and the energy barriers were calculated.

机译：半经验量子化学方法被用来模拟环戊环化的1（10）E，4E-germacranolide costunolide到杜鹃花苷。计算了有利于转型的共形国家和能源壁垒。

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《Chemistry of Natural Compounds》 |2001年第5期|共4页
作者
B.B.Khasenov; K.M.Turdybekov;
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正文语种 eng
中图分类化学;
关键词
sesquiterpene lactones; germacranolide; eudesmanolides; guaianolide; ransannular cyclization; quantum chemistry;

机译：倍半萜烯内酯;胚芽戊内酯;阿德曼醇内酯;愈创木酚内酯;花环环化;量子化学;

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1. Modelling transannular cyclization of 1(10)E,4E-germacranolide costunolide into eudesmane derivatives [J] . B.B.Khasenov, K.M.Turdybekov Chemistry of Natural Compounds . 2001,第5期

机译：将1（10）E，4E- Germacranolide costunolide转化为Eudesmane衍生物的环空环化模型
2. Transannular Cyclization of (4S,5S)-Germacrone-4,5-epoxide under Basic Conditions to Yield Eudesmane-Type Sesquiterpenes [J] . Masanori Kuroyanagi, Osamu Shirota, Setsuko Sekita Chemical and Pharmaceutical Bulletin . 2014,第7期

机译：（4S，5S）-Germacrone-4,5-环氧在基本条件下的环空环化反应生成Eudesmane型倍半萜烯
3. Transannular Cyclization of (4S,5S)-Germacrone-4,5-epoxide under Basic Conditions to Yield Eudesmane-Type Sesquiterpenes [J] . Chemical and Pharmaceutical Bulletin . 2014,第7期

机译：在基本条件下（4S，5S）-Germacrone-4,5-环氧化物环过环化生成Eudesmane型倍半萜烯
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机译：五环中的环状环化（5.4.0.0（2,6）.0（3,10）0（5,9）十一烷-8,11-二酮体系：重新研究

Modelling transannular cyclization of 1(10)E,4E-germacranolide costunolide into eudesmane derivatives

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