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首页> 外文期刊>The Journal of Chemical Physics >CHAOTIC DYNAMICS AND APPROXIMATE SEMICLASSICAL QUANTIZATION - ASSIGNING HIGHLY EXCITED VIBRATIONAL EIGENSTATES
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CHAOTIC DYNAMICS AND APPROXIMATE SEMICLASSICAL QUANTIZATION - ASSIGNING HIGHLY EXCITED VIBRATIONAL EIGENSTATES

机译:混沌动力学和近似半经典量化-分配高激发振动本征态

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摘要

The classical dynamics of highly chaotic vibrational dynamics is studied via the nature of resonance zones. It is demonstrated that the flow into and out of the resonance zones is complicated with some trajectories spending less than one period outside before reentering, referred to here as ''virtual recrossing.'' Despite the strong chaos, an approximate semiclassical quantization method based on the resonance zone structure can be used to generate eigenvalues to within a few percent of the quantum values well into the chaotic regime. The semiclassical quantization allows for the assignment of highly excited, strongly mixed vibrational eigenstates. (C) 1997 American Institute of Physics. [References: 40]
机译:通过共振区的性质研究了高度混沌振动动力学的经典动力学。事实证明,流入和流出共振区的过程很复杂,有些轨迹在重新进入之前花费的时间少于一个周期,这里称为“虚拟穿越”。尽管存在严重的混乱,但基于共振区结构可用于生成特征值,该特征值恰好进入混沌状态的量子值的百分之几之内。半经典量化允许分配高激发,强烈混合的振动本征态。 (C)1997美国物理研究所。 [参考:40]

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