首页> 外文期刊>The Journal of Chemical Physics >CALCULATIONS OF THE LOW TEMPERATURE PRESSURE BROADENING OF HCO+ ROTATIONAL SPECTRAL LINES BY H-2
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CALCULATIONS OF THE LOW TEMPERATURE PRESSURE BROADENING OF HCO+ ROTATIONAL SPECTRAL LINES BY H-2

机译:H-2计算HCO +旋转谱线的低温压力扩散

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Calculations on the pressure broadening by H-2 of HCO+ rotational spectral lines have been performed in the temperature range 11-300 K. Recent low temperature measurements of the pressure broadening of the J=3-2 line at 11-30 K are reproduced to within 10-20% by the results of a capture theory. The results of Anderson theory in this temperature range, on the other hand, are low by a factor of up to approximate to 3 compared with experiment. A hybrid method is proposed, which converges to the capture theory at low temperatures and the Anderson theory at high temperatures. (C) 1996 American Institute of Physics. [References: 26]
机译:已经在11-300 K的温度范围内对HCO +旋转谱线的H-2压力展宽进行了计算。最近在11-30 K的情况下,对J = 3-2线的压力展宽的低温测量结果被再现为:捕获理论的结果在10-20%之内。另一方面,在这个温度范围内,安德森理论的结果与实验相比降低了大约3倍。提出了一种混合方法,该方法收敛于低温下的俘获理论和高温下的安德森理论。 (C)1996年美国物理研究所。 [参考:26]

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