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首页> 外文期刊>The Journal of Chemical Physics >A TRANSITION FROM SHEAR-INDUCED ORDER TO SHEAR-INDUCED DISORDER IN BLOCK COPOLYMERS
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A TRANSITION FROM SHEAR-INDUCED ORDER TO SHEAR-INDUCED DISORDER IN BLOCK COPOLYMERS

机译:嵌段共聚物从剪切顺序到剪切顺序的转变

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摘要

The effect of steady shear flow on a weakly ordered block copolymer material was examined by in situ small angle neutron scattering. We demonstrate this material undergoes a transition from shear-induced ordering to shear-induced disordering at a fixed temperature above the quiescent disordering temperature. Current theories, which assume that the primary effect of shear flow on block copolymers is to suppress disordered concentration fluctuations, can only predict shear-induced ordering. Our results indicate that the coupling between flow and microstructure is not unique and that it can change qualitatively with shear rate. (C) 1996 American Institute of Physics. [References: 12]
机译:通过原位小角度中子散射检查了稳定剪切流对弱有序嵌段共聚物材料的影响。我们证明了这种材料在高于静态无序温度的固定温度下经历了从剪切诱导的有序到剪切诱导的无序的过渡。当前的理论认为剪切流对嵌段共聚物的主要影响是抑制无序的浓度波动,目前的理论只能预测剪切引起的有序化。我们的结果表明,流动与微观结构之间的耦合不是唯一的,并且可以随剪切速率而定性地变化。 (C)1996年美国物理研究所。 [参考:12]

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