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New means of spatially manipulating molecules with light

机译:用光在空间上操纵分子的新方法

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We develop a general framework for describing the interaction of molecules with a nonperturbative intensity gradient and note several limits, including the two-level Hamiltonian of atom trapping and the quasistatic Hamiltonian of molecular optics. The theory is used to propose a new molecular optics scheme which complements previous work in the area of spatial manipulation of molecules in intense fields by introducing the possibility of reflecting molecules with light. Repulsive interaction obtains in the limit of small level spacings as compared to the field frequency, attained by exciting the molecules to high Rydberg states. Some of the potential applications of the repulsive interaction are illustrated and others are noted. We address the problem of molecular alignment in intense laser fields and describe the possibility of simultaneously focussing the center-of-mass motion of molecules and aligning their figure axis after exit from the laser focus, under field-free conditions.
机译:我们开发了一个用于描述分子与非扰动强度梯度相互作用的通用框架,并注意到几个限制,包括原子俘获的两级哈密顿量和分子光学的准静态哈密顿量。该理论用于提出一种新的分子光学方案,该方案通过引入用光反射分子的可能性来补充在强场中分子的空间操纵领域中的先前工作。通过将分子激发到高的里德堡态,与场频相比,排斥性相互作用只获得了较小的能级间距。图示了排斥相互作用的一些潜在应用,并指出了其他一些潜在应用。我们解决了在强激光场中分子对准的问题,并描述了在无场条件下同时聚焦分子的质心运动和从激光焦点退出后对准分子的图轴的可能性。

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