SYNTHESIS OF 2,3-DIHYDROPERIMIDINE KETONES

Borovlev IV; Demidov OP

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SYNTHESIS OF 2,3-DIHYDROPERIMIDINE KETONES

机译：2,3-二氢嘧啶酮的合成

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Ketones derived from unsubstituted 2,3-dihydroperimidine were obtained by the selective reduction of the corresponding acylperimidines. The direct acylation of 2,3-dihydroperimidine in PPA is accompanied by dehydrogenation and leads to 4(9)-acylperimidines. The spectral characteristics of these products were discussed.

机译：通过选择性还原相应的酰基perimidines，可以得到衍生自未取代的2，3-二氢perimidine的酮。 PPA中2，3-二氢过氧亚丙基的直接酰化作用伴随着脱氢作用，并导致4（9）-酰基过氧亚氨酸。讨论了这些产物的光谱特征。

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《Chemistry of heterocyclic compounds》 |2009年第6期|共5页
作者
Borovlev IV; Demidov OP;
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正文语种 eng
中图分类杂环化合物;
关键词
sodium borohydride; 2; 3-dihydroperimidine; perimidine; polyphosphoric; acid; acylation;

机译：硼氢化钠;2;3-二氢哌啶;嘧啶;多磷酸;酸;酰化;

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1. SYNTHESIS OF 2,3-DIHYDROPERIMIDINE KETONES [J] . Borovlev IV, Demidov OP Chemistry of heterocyclic compounds . 2009,第6期

机译：2,3-二氢嘧啶酮的合成
2. Synthesis of ruthenium (II) complexes containing a dihydroperimidine-derived phosphine ligand and their application in transfer hydrogenation of ketones [J] . Qi Fu, Lei Zhang, Tao Yi Inorganic Chemistry Communications . 2013,第Null期

机译：含二氢过氧亚胺的膦配体的钌（II）配合物的合成及其在酮转移加氢中的应用
3. Nano-gamma-Al2O3/SbCl5: an efficient catalyst for the synthesis of 2,3-dihydroperimidines [J] . Bamoniri Abdolhamid, Mirjalili Bi Bi Fatemeh, Saleh Sepideh RSC Advances . 2018,第11期

机译：Nano-Gamma-Al2O3 / SbCl5：合成2,3-二氢丙烯尼啶的有效催化剂
4. Process Design for production of 1,3-Butadiene and Methyl Ethyl Ketone from Dehydration of 2,3-Butanediol [C] . Yeong-Gak Yoon, Dae-Sung-Song, Chul-Jin Lee European Symposium on Computer Aided Process Engineering . 2017

机译：从2,3-丁二醇脱水生产1,3-丁二烯和甲基乙基酮的过程设计
5. Synthesis of conjugates of L-fucose and ortho-carborane as potential agents for boron neutron capture therapy, and, Synthesis of 2,3-dideoxy-2,3-methanoribofuranoside glycosyl donors and a study of their use in stereocontrolled glycosylation reactions. [D] . Basak, Prakriti. 2003

机译：合成L-岩藻糖和邻位碳硼烷作为硼中子俘获治疗的潜在药物，以及2,3-二脱氧-2,3-甲基呋喃呋喃糖苷糖基供体的合成及其在立体控制糖基化反应中的应用研究。
6. New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones [O] . José A Fuentes, Scott D Phillips, Matthew L Clarke 2012

机译：用于钌催化酮的对映选择性氢化的新膦二胺和膦氨基氨基醇三齿配体以及通过不对称还原氰基酮实现的简洁内酯合成
7. Stereospecific 3+2 cycloaddition of 1,2-cyclopropanated sugars and ketones catalyzed by SnCl4: an efficient synthesis of multi-substituted perhydrofuro2,3-bfurans and perhydrofuro2,3-bpyrans [O] . Ma Xiaofeng, Zhang Jichao, Tang Qin, 2014

机译：SnCl4催化1,2,2-环丙烷化糖和酮的立体特异性3 + 2环加成反应：多取代全氢呋喃2,3-b呋喃和全氢呋喃2,3-b吡喃的有效合成

SYNTHESIS OF 2,3-DIHYDROPERIMIDINE KETONES

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