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首页> 外文期刊>Chemistry Letters >Structural Change of a Cast Film of Amphiphilic Ruthenium(II) Cyano Complex Caused by Electrochemical Oxidation
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Structural Change of a Cast Film of Amphiphilic Ruthenium(II) Cyano Complex Caused by Electrochemical Oxidation

机译:电化学氧化导致两亲性钌(Ⅱ)氰配合物流延膜的结构变化

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摘要

An amphiphilic ruthenium(II) cyano complex, (N(C_2H_5)_4)_2-[Ru(dc 18bpy)(CN)_4] (dc 18bpy - 4,4'=dioctadecyl-2,2'-bi-pyridine), was prepared by photo-induced ligand exchange. The X-ray diffraction patterns were compared before and after the electrochemical oxidation of the cast film on an ITO electrode. The film had a layered srucure, whose interlayer distance changed irreversibly from 4.60nm to 4.01 nm when the central Ru(II) ion was was oxidized to Ru(III).
机译:两亲性钌(II)氰基络合物,(N(C_2H_5)_4)_2- [Ru(dc 18bpy)(CN)_4](dc 18bpy-4,4'= dioctadecyl-2,2'-bi-pyridine),通过光诱导的配体交换制备。在流延膜在ITO电极上进行电化学氧化之前和之后,比较了X射线衍射图。该膜具有层状结构,当中心Ru(II)离子被氧化成Ru(III)时,其层间距离从4.60nm不可逆地变化到4.01nm。

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