Cellulose 3,5-Dimethylphenylcarbamate Immobilized onto Silica Gel via Copolymerization with a Vinyl Monomer and Its Chiral Recognitio Ability as a Chiral Stationary Phase for HPLC

摘要

A new cellulose phenylcarbamate derivative having a vinyl group at the 6-position was synthesized and immobilized onto silica gel via radical copolymerization with styrene. The immo-bilization was efficiently attained using a small amount of styrene. The chiral recogition abilities of the immobilized chiral stationary phase (CSP) were similar to those of the CSP coated on silica gel.