Stereospecific Ring-Opeing Metathesis Polymerization of endo-Dicyclopentadiene by Schrock-Hoveyda Catalyst and Novel Mo-and W-based Complexes.Development of Crystalline Hydrogenated Poly(endo-dicyclopentadiene)

摘要

Novel crystalline polymer,crystalline hydrogenated poly (endo-dicyclopentadiene),was developed on the basis of the development of new cis-and iso-specific ROMP catalysts such as MoO(rac-5,5',6,6'-Me_4-3,3'-t-biphenolate)_2