Self-assembled Dendrimer-bound Pd(II) Complexes via Acid-base Interactions and their Catalysis for Allylic Amination

摘要

The Pd complexes were noncovalently attached on the periphery of poly(propyleneimine) dendrimers based on acid-base interactions.Teh dendritic Pd complexes were found to possess catalytic activities for allylic amination,and to be able to mimick the catalytic activity of the analogous monomeric Pd complex catalyst.