Mild, Efficient and Selective Nitration of Anilides, Non-Activated and Moderately Activated Aromatic Compounds with Ammonium Molybdata and Niric Acid as a New Nirating Agent

摘要

Ammonium molybdata [Mo(VI)] is operationally simple, environmentally safe and inexpensive reagent. Regioselective ntiration of anilides, non-activated and moderately activated aromatic compounds could be afforded by employing ammonium molybdate and nitric acid as mild and effective nitrating agent. This procedure works efficiently under reflex conditions to prepare monontroderivatives of anilides, non-activated and moderately activated aromatic compounds in good to excellent yield with high regioselectivity.