Synthesis and structure of cyclotrigermenium salt of the tetrakis{3,5-bis(tri-fluoromethyl)phenyl}borate anion. A stable free germyl cation in the condensed phase

Ichinohe M.; Sekiguchi A.; Fukaya N.

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Synthesis and structure of cyclotrigermenium salt of the tetrakis{3,5-bis(tri-fluoromethyl)phenyl}borate anion. A stable free germyl cation in the condensed phase

机译：四{3,5-双（三氟甲基）苯基}硼酸根阴离子的环三锗盐的合成与结构。缩合相中稳定的游离生殖腺阳离子

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The reaction of tetrakis(tri-t-butylsilyl)cyclotrigermene with Ph3C+.[3,5-(CF3)(2)C6H3]B- (TFPB) and Ph3C+.(C6F5)(4)B- (TPFPB) in benzene produced the stable free tris(tri-t-butylsilyl)cyclotrigermenium ion (2a) with the corresponding tetraarylborate as a counter anion. The crystal structure of 2a TFPB reveals a free germyl cation with a 2a . electron system. [References: 33]

机译：四（三叔丁基甲硅烷基）环三锗烯与Ph3C +。[3,5-（CF3）（2）C6H3] B-（TFPB）和Ph3C +。（C6F5）（4）B-（TPFPB）的反应在苯中生成稳定的游离三（三叔丁基甲硅烷基）环三锗离子（2a），并带有相应的四芳基硼酸酯作为抗衡阴离子。 2a TFPB的晶体结构显示具有2a的游离生殖腺阳离子。电子系统。 [参考：33]

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《Chemistry Letters》 |1998年第10期|共2页
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Ichinohe M.; Sekiguchi A.; Fukaya N.;
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中图分类化学;化学工业;
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1. Synthesis and structure of cyclotrigermenium salt of the tetrakis{3,5-bis(tri-fluoromethyl)phenyl}borate anion. A stable free germyl cation in the condensed phase [J] . Ichinohe M., Sekiguchi A., Fukaya N. Chemistry Letters . 1998,第10期

机译：四{3,5-双（三氟甲基）苯基}硼酸根阴离子的环三锗盐的合成与结构。缩合相中稳定的游离生殖腺阳离子
2. Cyclotrigermenium Ion by Oxidation of Cyclotrigermene with Trityl Tetrakis {3,5-Bis(Trifluoromethyl)Phenyl}Borate and Trityl Tetrakis(Pentafluoro-Phenyl)Borate. A Stable Free Germyl Cation in the Condensed Phase [J] . Akira Sekiguchi, Norihisa Fukaya, Masaaki Ichinohe Phosphorus, Sulfur, and Silicon and the Related Elements . 1999,第0期

机译：通过用三苯甲基四（3，5-双（三氟甲基）苯基）硼酸酯和三苯甲基四（五氟-苯基）硼酸酯氧化环三锗烯而形成环三锗离子。缩合相中稳定的游离Germyl阳离子
3. Synthesis and Structure of Cyclotrigermenium Salts of Tetrakis{3, 5-bis(trifluoromenthyl)phenyl}borate, Tetrakis(pentafluorophenyl)borate and Tetrakis{4-[tert-butyl(dimethyl)silyl]-2, 3, 5, 6-tetrafluorophenyl}borate: A Stable Free Germyl Cation in t [J] . Akira Sekiguchi, Norihisa Fukaya, Masaaki Ichinohe, European journal of inorganic chemistry . 2000,第6期

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4. Development of a soft ionization technique in nonpolar liquid with lithium tetrakis(3,5-bis(trifluoromethyl)-phenyl)borate [C] . A. Takamizawa, N. Niizuma, T. Korenaga American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

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机译：可见光光催化剂的根基阳离子酰胺 - 桤木环加法：Tris（2,2'-双嘧嘧啶）钌（II）双（四（三氟甲基）苯基）硼酸盐）的制备）
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机译：Trityl Tetrakis（3,5-双（三氟甲基）苯基） - 硼酸盐：一种新的氢化物提取试剂

Synthesis and structure of cyclotrigermenium salt of the tetrakis{3,5-bis(tri-fluoromethyl)phenyl}borate anion. A stable free germyl cation in the condensed phase

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