Supramolecular inclusion complexes of fullerenes using cyclotriveratrylene derivatives with aromatic pendants

摘要

CTV derivatives with aromatic pendants were synthesized and their inclusion abilities for C-60 and C-70 were examined by UV spectroscopy. CTV derivative with three N-methylpyrrole pendants showed the highest association constant for C-60 (48000 dm(3)mol(-1) in benzene). The structure of inclusion complex for C-60 with CTV derivative which has six benzoyl pendants has been determined by single-crystal X-ray diffraction. [References: 17]