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首页> 外文期刊>Chemistry Letters >The crystal structure and magnetic properties of Cu-II-Ni-II heterodinuclear complex with N,N '-bis(2-pyridyl-ethyl)-oxamide dianion
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The crystal structure and magnetic properties of Cu-II-Ni-II heterodinuclear complex with N,N '-bis(2-pyridyl-ethyl)-oxamide dianion

机译:N,N'-双(2-吡啶基-乙基)-乙酰胺二价阴离子Cu-II-Ni-II异双核配合物的晶体结构和磁性

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摘要

A new Cu-II-Ni-II heterodinuclear complex [Cu(PEoxd) Ni(bpy)(2)](ClO4)(2). 1/2H(2)O has been synthesized and its structure determined by single crystal X-ray analysis. Crystal data: space group P2(1)/c with a = 9.226(2) Angstrom, b = 30.857(6) Angstrom, c = 14.241(3) Angstrom, and beta = 97.36(3)degrees, V = 4021(2) Angstrom(3), Z = 4. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic. [References: 16]
机译:一种新的Cu-II-Ni-II异双核络合物[Cu(PEoxd)Ni(bpy)(2)](ClO4)(2)。 1 / 2H(2)O已合成,其结构通过单晶X射线分析确定。晶体数据:a = 9.226(2)埃,b = 30.857(6)埃,c = 14.241(3)埃和beta = 97.36(3)度,V = 4021(2)的空间群P2(1)/ c )埃(3),Z =4。磁测量表明,总体磁性能为弱反铁磁。 [参考:16]

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