A Novel Bi-Metal Ni~(II)Cd~(II)Supramolecular Structure with4-Hydroxypyridine Ligands, Cd~(II)(4-OHpy)_2}{Ni~(II)(CN))4}],and Deprotonated 3-Hydroxypyridine Ligands, Cd~(II)_3(3-O-py)_2(mea)_2}{Ni~(II)(CN)_4}_2]

摘要

Synthesis and crystal structures of new bimetallicpolynuclear complexes in 2-dimensional (2D) architectures,If Cdn(4-0Hpy)2} {Nin(CN)4}] (4-OHpy = 4-hydroxypyri-dine) (1) and [ { Cd113(3-0-py)2(mea)2} { Nill(CN)4}21 (3-0-py = pyridin-3-onato anion, mea = monoethanolamine)(2) are described. These compounds are prepared by thesame method. However, hydroxypyridine ligands are differ-ent, thus these structures differ.