Two Neutral Open-framework Metal Phosphites with Ten-ring Channels Constructed by Three-, Four-, and Five-connected Centers

摘要

Neutral open-structured metal phosphites of Al and In are hydrothermally synthesized; they are structural analogues that constructed by HPO3 and MO6 groups with intersecting eight-and 10-ring channels. The two metal sites serve as four- and five-connected centers, respectively, with the rest oxygen atoms belonging to the coordinated water molecules.