Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

Sugimoto H.; Tanaka K.; Tsuge K.

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Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

机译：邻苯二酚和三联吡啶配体的七配位rh（V）配合物的新型分子内重排

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Novel hepta-coordinate rhenium(V) complex with two 3,6-di-tert-butyl-catecholate and one terpyridine ligands was synthesized and structurally characterized. Temperature dependent H-1 NMR spectra reveal dynamic behavior of the complex resulting from the site exchange of an equatrial position between two catecholate ligands. [References: 8]

机译：合成了具有两个3,6-二叔丁基-儿茶酚酸酯和一个吡啶吡啶配体的新型七坐标rh（V）配合物，并对其结构进行了表征。温度相关的H-1 NMR光谱揭示了复合物的动态行为，这是由于两个儿茶酚配体之间的赤道位置发生位置交换而引起的。 [参考：8]

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《Chemistry Letters》 |1998年第8期|共2页
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Sugimoto H.; Tanaka K.; Tsuge K.;
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中图分类化学;化学工业;
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1. Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands [J] . Sugimoto H., Tanaka K., Tsuge K. Chemistry Letters . 1998,第8期

机译：邻苯二酚和三联吡啶配体的七配位rh（V）配合物的新型分子内重排
2. Preparation and characterization of rhenium(I) dicarbonyl complexes based on the meridionally-coordinated terpyridine ligand [J] . Daniel R. Black, Sean E. Hightower Inorganic Chemistry Communications . 2012,第Null期

机译：基于子午配位三联吡啶配体的of（I）二羰carbonyl（I）配合物的制备和表征
3. Synthesis and dynamic NMR studies of fluxionality in rhenium(I), platinum(II) and platinum(IV) complexes of 'back-to-back' 2,2 ': 6 ',2 ''-terpyridine ligands [J] . Gelling A., Orrell KG., Osborne AG., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第20期

机译：back背对背2,2'：6'，2'-三联吡啶配体的（（I），铂（II）和铂（IV）络合物中的通量的合成和动态NMR研究
4. Highly Efficient pH-Induced Intramolecular Quenching of Luminescence in rhenium complexes Containing the Hydroxypyridine Ligand. [C] . William D.Bare, Nathan H.Mack, J.Ngt, Conference on water, ground, and air pollution monitoring and remediation . 2001

机译：高效的pH-诱导含有羟基吡啶配体的铼配合物中发光的分子内猝灭。
5. I. Symmetrical ligand bridged bimetallic complexes of rhenium(I): Implications for electrocatalytic reduction of carbon dioxide. II. Unimolecular excited state relaxation pathways in polypyridyl complexes of rhenium(I). [D] . Baiano, John Augustus. 1992

机译：I. ligand的对称配体桥联双金属络合物（I）：对电催化还原二氧化碳的影响。二。 poly（I）聚吡啶配合物中的单分子激发态弛豫途径。
6. Rhenium(I) Carbonyl Complexes of 246-Tris(2-pyridyl)-135-triazine (TPT). Rhenium(I)-Promoted Methoxylation of the Triazine Ring Carbon Atom in Dinuclear Rhenium Complexes [O] . Xiaoyuan Chen, Frank J. Femia, John W. Babich, -1

机译：246-三（2-吡啶基）-135-三嗪（TPT）的Carbon（I）羰基配合物。 nu（I）促进双核R配合物中三嗪环碳原子的甲氧基化
7. Control of Photochemical, Photophysical, Electrochemical, and Photocatalytic Properties of Rhenium(I) Complexes Using Intramolecular Weak Interactions between Ligands [O] . -1

机译：用配体与分子分子弱相互作用控制铼（I）配合物的光化学，光药，电化学和光催化性质
8. pH-Induced Intramolecular Quenching. Ligand-Bridged Complexes Containing Osmium and Ruthenium [R] . Loeb, B., Neyhart, G. A., Worl, L. A., 1989

机译：pH诱导的分子内猝灭。含有锇和钌的配体桥联配合物

Novel intramolecular rearrangement of hepta-coordinate rhenium(V) complex with catecholato and terpyridine ligands

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