A novel BEDT-TTF-based organic conducting salt with a ferrocene-containing dianion, alpha-(BEDT-TTF)(4)(Fe(Cp-CONHCH2SO3)(2))center dot 4H(2)O

Furuta K; Akutsu H; Yamada J; Nakatsuji S

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A novel BEDT-TTF-based organic conducting salt with a ferrocene-containing dianion, alpha-(BEDT-TTF)(4)(Fe(Cp-CONHCH2SO3)(2))center dot 4H(2)O

机译：一种新型的基于BEDT-TTF的有机导电盐，含二茂铁的二价阴离子，α-（BEDT-TTF）（4）（Fe（Cp-CONHCH2SO3）（2））中心点4H（2）O

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We have prepared a new organic dianion containing the ferrocene derivative, Fe(C5H4-CONHCH2SO3-)(2), as a PPh4 salt. Cyclic voltammetry indicates its oxidation potential is 0.14 V higher than that of BEDT-TTF. Electrocrystallization with BEDT-TTF gave the title compound. Its crystal structure and physical properties are reported.

机译：我们准备了一种新的有机二价阴离子，其中含有二茂铁衍生物Fe（C5H4-CONHCH2SO3-）（2）作为PPh4盐。循环伏安法表明其氧化电位比BEDT-TTF高0.14V。用BETT-TTF电结晶得到标题化合物。报告了其晶体结构和物理性质。

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《Chemistry Letters》 |2004年第9期|共2页
作者
Furuta K; Akutsu H; Yamada J; Nakatsuji S;
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正文语种 eng
中图分类化学;
关键词
CHARGE-TRANSFER COMPLEXES; TRANSITION; CHANNELS; METAL; SPIN;

机译：电荷转移复合物;过渡;通道;金属;自旋;

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1. A novel BEDT-TTF-based organic conducting salt with a ferrocene-containing dianion, alpha-(BEDT-TTF)(4)(Fe(Cp-CONHCH2SO3)(2))center dot 4H(2)O [J] . Furuta K, Akutsu H, Yamada J, Chemistry Letters . 2004,第9期

机译：一种新型的基于BEDT-TTF的有机导电盐，含二茂铁的二价阴离子，α-（BEDT-TTF）（4）（Fe（Cp-CONHCH2SO3）（2））中心点4H（2）O
2. New BEDT-TTF-based Organic Conductor Including an Organic Anion Derived from the TEMPO Radical,alpha-(BEDT-TTF)_3(TEMPO-NHCOCH_2SO_3)_2(centre dot)6H_2O [J] . Hiroki Akutsu, Jun-ichi Yamada, Shinichi Nakatsuji Chemistry Letters . 2003,第12期

机译：新的基于BEDT-TTF的有机导体，包括来自TEMPO自由基的有机阴离子α-（BEDT-TTF）_3（TEMPO-NHCOCH_2SO_3）_2（中心点）6H_2O
3. Elaboration, crystal structure, vibrational, optical properties, thermal analysis and theoretical study of a new inorganic-organic hybrid salt [C4H12N2](4)center dot Pb2Cl11 center dot Cl center dot 4H(2)O [J] . Journal of Molecular Structure . 2020,第期

机译：新型无机 - 有机杂交盐的阐述，晶体结构，振动，光学性质，热分析和理论研究[C4H12N2]（4）中心点PB2CL11中心点CL中心点4H（2）O.
4. INTER-LAYER MAGNETORESISTANCE IN MULTILAYER MASSLESS DIRAC FERMIONS SYSTEM alpha-(BEDT-TTF)_(2)I_(3) [C] . N. TAJIMA, S. SUGAWARA, Y. NISHIO, International Symposium on Foundations of Quantum Mechanics in the Light of New Technology . 2009

机译：多层无麻子泥土晶片系统中层间磁阻系统α-（Bedt-TTF）_（2）I_（3）
5. Thin polytype inclusions in 4H silicon carbide epitaxial films and isotope and anharmonic effects in carbon-hydrogen vibrational centers of silicon carbide. [D] . Bai, Song. 2003

机译：4H碳化硅外延膜中的薄多型夹杂物以及碳化硅的碳氢振动中心的同位素和非谐效应。
6. Bottom-up on-crystal in-chip formation of a conducting salt and a view of its restructuring: from organic insulator to conducting switch through microfluidic manipulation [O] . Josep Puigmartí-Luis, Markos Paradinas, Elena Bailo, 2015

机译：自下而上的晶体内片上导电盐的形成及其重组的观点：从有机绝缘体到通过微流控操纵进行转换
7. Static and dynamic interaction between pi and d electrons in organic superconductor beta ''-(BEDT-TTF)(4)(H3O)Fe(C2O4)(3) center dot C6H5Br studied by C-13 NMR spectroscopy [O] . Ihara Y., Futami Y., Kawamoto A., 2016

机译：通过C-13 NMR光谱研究有机超导体β''-（BEDT-TTF）（4）（H3O）Fe（C2O4）（3）中心点C6H5Br中pi电子和d电子之间的静态和动态相互作用
8. New ambient pressure organic superconductors: alpha-(BEDT-TTF)(sub 2)(NH(sub 4))Hg(SCN)(sub 4), beta m-(BEDO-TTF)(sub 3)Cu(sub 2)(NCS)(sub 3), and kappa-(BEDT-TTF)(sub 2)Cu(N(CN)(sub 2))Br. [R] . Wang, H. H., Beno, M. A., Carlson, K. D., 1990

机译：新的环境压力有机超导体：α-（BEDT-TTF）（sub 2）（NH（sub 4））Hg（sCN）（sub 4），beta m-（BEDO-TTF）（sub 3）Cu（sub 2）（NCs）（sub 3）和kappa（BEDT-TTF）（sub 2）Cu（N（CN）（sub 2））Br。

A novel BEDT-TTF-based organic conducting salt with a ferrocene-containing dianion, alpha-(BEDT-TTF)(4)(Fe(Cp-CONHCH2SO3)(2))center dot 4H(2)O

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