Preparation of mixed-metal polynuclear complexes by stepwise phosphine-bridging reaction

Aizawa S; Kawamoto T; Saito K

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Preparation of mixed-metal polynuclear complexes by stepwise phosphine-bridging reaction

机译：逐步膦桥联反应制备混合金属多核配合物

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The phosphine-bridged Pd(II)-Pt(II)-Pd(II) trinuclear and Rh(III)-Pd(II)-Pt(II)-Pd(II)-Rh(III) pentanuclear complexes with tris[2-(diphenylphosphino)ethyl]phosphine (PP3) ligands were successfully prepared by stepwise phosphine-bridging reaction of the terminal phosphino groups of the PP3 ligands on the Pd(II) cores.

机译：膦桥联的带有tris的Pd（II）-Pt（II）-Pd（II）三核和Rh（III）-Pd（II）-Pt（II）-Pd（II）-Rh（III）五核配合物通过在Pd（II）核上的PP3配体的末端膦基逐步进行膦基桥接反应，成功制备了-（二苯基膦基）乙基]膦（PP3）配体。

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《Chemistry Letters》 |2004年第10期|共2页
作者
Aizawa S; Kawamoto T; Saito K;
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正文语种 eng
中图分类化学;
关键词
PALLADIUM(II) COMPLEXES; LIGAND; TRIS(2-(DIPHENYLPHOSPHINO)ETHYL)PHOSPHINE;

机译：钯（II）络合物;配体;三（2-（二苯膦基）乙基）膦;

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1. Preparation of mixed-metal polynuclear complexes by stepwise phosphine-bridging reaction [J] . Aizawa S, Kawamoto T, Saito K Chemistry Letters . 2004,第10期

机译：逐步膦桥联反应制备混合金属多核配合物
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Preparation of mixed-metal polynuclear complexes by stepwise phosphine-bridging reaction

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