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Non-linear rheology of lamellar liquid crystals

机译:层状液晶的非线性流变学

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We measure the non-linear relation between the shear stress and shear rate in the lyotropic lamellar phase of C12E5/water system. The measured shear thinning exponent changes with the surfactant concentration. A simple rheology theory of a lamellar or smectic phase is proposed with a prediction. (gamma) over dot similar to sigma(3/2), where. (gamma) over dot is the shear rate and sigma is the shear stress. We consider that the shear flow passed through the defect structure causes the main dissipation. As the defect line density varies with the shear rate, the shear thinning arises. The defect density is estimated by the dynamic balance between the production and annihilation processes. The defect production is caused by the shear-induced layer undulation instability. The annihilation occurs through the shear-induced defect collision process. Further flow visualization experiment shows that the defect texture correlates strongly with the shear thinning exponent.
机译:我们测量了C12E5 /水系统的溶致层状相中剪切应力与剪切速率之间的非线性关系。测得的剪切稀化指数随表面活性剂浓度而变化。提出了具有层状或近晶相的简单流变学理论,并进行了预测。类似于sigma(3/2)的点上的(γ),其中。点上的γ是剪切速率,而sigma是剪切应力。我们认为通过缺陷结构的剪切流会引起主要的耗散。当缺陷线密度随剪切速率变化时,剪切变稀出现。通过生产和is灭过程之间的动态平衡来估算缺陷密度。缺陷产生是由剪切引起的层起伏不稳定性引起的。 the没通过剪切引起的缺陷碰撞过程发生。进一步的流动可视化实验表明,缺陷组织与剪切稀化指数密切相关。

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