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Electric-field-induced polarization of the layer of condensed ions on cylindrical colloids

机译:电场作用下圆柱状胶体上凝聚离子层的极化

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摘要

In concentrated suspensions of charged colloids, interactions between colloids can be induced by an external electric field through the polarization of charge distributions (within the diffusive double layer and the layer of condensed ions) and/or electro-osmotic flow. In case of rod-like colloids, these field-induced inter-colloidal interactions have recently been shown to lead to anomalous orientation perpendicular to the external field, and to phase/state transitions and dynamical states, depending on the field amplitude and frequency of the external field. As a first step towards a (semi-) quantitative understanding of these phenomena, we present a linear-response analysis of the frequency-dependent polarization of the layer of condensed ions on a single, long and thin cylindrical colloid. The in-phase and out-phase response functions for the charge distribution and the electric potential are calculated for arbitrary orientation of the cylindrical colloid. The frequency-dependent degree of alignment, which is proportional to the electric-field-induced birefringence, is calculated as well, and compared to experiments on dilute fd virus suspensions.
机译:在带电胶体的浓缩悬浮液中,胶体之间的相互作用可以由外部电场通过电荷分布的极化(在扩散双层和冷凝离子层内)和/或电渗流来诱导。对于棒状胶体,最近已证明这些场诱导的胶体间相互作用会导致垂直于外场的异常取向,并导致相/状态转变和动态状态,具体取决于场振幅和频率。外部领域。作为对这些现象进行(半)定量理解的第一步,我们对单个,长而细的圆柱状胶体上的冷凝离子层的频率相关极化进行了线性响应分析。对于圆柱状胶体的任意取向,计算出电荷分布和电势的同相和异相响应函数。还计算了与频率有关的对准度,该对准度与电场引起的双折射成正比,并与稀释的fd病毒悬浮液的实验进行了比较。

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