Induction of Optical Activity in Oligosilanes by Chiral Wrapping with beta-l,3-Glucan (Schizophyllan)

摘要

Linear oligosilanes form inclusion complexes with schizo-phyllan to induce a preferential helical conformation within the chiral environment constructed by wrapping with schizo-phyllan.Recently,controlling the helical structure of macromole-cules has attracted a great deal of interest.