The uncertainty of a result from a linear calibration

摘要

The standard error of a result obtained from a straight line calibration is given by a well known ISO-endorsed expression. Its derivation and use are explained and the approach is extended for any function that is linear in the coefficients, with an example of a weighted quadratic calibration in ICPAES. When calculating the standard error of an estimate, if QC data is available it is recommended to use the repeatability of the instrumental response, rather than the standard error of the regression, in the equation.