A new method for the synthesis of beta,gamma-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin

Loh TP.; Yin Z.; Cao GQ.

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >A new method for the synthesis of beta,gamma-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin

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A new method for the synthesis of beta,gamma-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin

机译：在一氧化碳和胺存在下，由钯催化的烯丙基碳酸酯合成β，γ-不饱和酰胺的新方法：全合成抗llatoxin

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The reaction of alpha,beta-unsaturated carbonates was carried out in DMF in the presence of PdCl2/dppb (5 mol%), CO and L-alanine at 65 degrees C for 4 days to give the beta, gamma-unsaturated amide intermediate of antillatoxin in good yield. (C) 1999 Published by Elsevier Science Ltd. All rights reserved. [References: 15]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1999年第13期|共4页
作者
Loh TP.; Yin Z.; Cao GQ.;
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正文语种 eng
中图分类有机化学;
关键词
Palladium and compounds; Carbonylation; Amides; Decarboxylation-carbonylation; Esters;

机译：钯及其化合物;羰基化;酰胺;脱羧羰基;酯;

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1. A new method for the synthesis of beta,gamma-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin [J] . Loh TP., Yin Z., Cao GQ. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第13期

机译：在一氧化碳和胺存在下，由钯催化的烯丙基碳酸酯合成β，γ-不饱和酰胺的新方法：全合成抗llatoxin
2. Ketenimines from Isocyanides and Allyl Carbonates: Palladium-Catalyzed Synthesis of beta,gamma-Unsaturated Amides and Tetrazoles [J] . Qiu Guanyinsheng, Mamboury Mathias, Wang Qian, Angewandte Chemie . 2016,第49期

机译：异氰酸酯和烯丙基碳酸酯的酮亚胺：钯催化的β，γ-不饱和酰胺和四唑的合成
3. Synthesis of Secondary Amides through the Palladium(II)- Catalyzed Aminocarbonylation of Arylboronic Acids with Amines or Hydrazines and Carbon Monoxide [J] . Jin Zhang, Yuqiang Ma, Yangmin Ma European journal of organic chemistry . 2018,第14期

机译：通过钯（II）催化芳基硼酸与胺或肼和一氧化碳催化氨基羰基化的仲酰胺的合成
4. Hydroxyapatite-supported Palladium-catalyzed Allylation of Carbon Nucleophiles with Allylic Carbonates [C] . Yukiko Nakajima, Yoshiro Masuyama Symposium on Organometallic Chemistry . 2007

机译：羟基磷灰石支持的钯催化碳亲核催化烯丙基碳酸酯
5. Part I. Development of new organic synthetic methods: Palladium and copper catalyzed carbon-carbon, carbon-sulfur, carbon-nitrogen, and carbon-oxygen bond formation as well as DABCO-mediated stereospecific synthesis of acrylate ethers and amines. Part II. Design, synthesis and SAR studies of new classes of agents to treat drug-resistant bacteria, anthrax and tuberculosis infections. [D] . Kabir, Mohd Shahjahan. 2011

机译：第一部分：新的有机合成方法的开发：钯和铜催化的碳-碳，碳-硫，碳-氮和碳-氧键的形成，以及DABCO介导的丙烯酸酯醚和胺的立体有择合成。第二部分新型药物的设计，合成和SAR研究，用于治疗抗药性细菌，炭疽和肺结核感染。
6. Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates [O] . Eric J. Alexy, Haiming Zhang, Brian M. Stoltz -1

机译：无环季铵盐中心的催化对映选择性合成：完全取代的无环烯醇碳酸酯的钯催化脱羧烯丙基烷基化
7. A Facile Method for the Synthesis of Thiocarbamates: Palladium-Catalyzed Reaction of Disulfide, Amine, and Carbon Monoxide [O] . -1

机译：用于合成硫代氨基甲酸酯的容易方法：二硫化物，胺和一氧化碳的钯催化反应

A new method for the synthesis of beta,gamma-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin

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