Sequential hydroformylation aldol addition reactions of beta,gamma-unsaturated ketones and their derivatives

Hollmann C.; Eilbracht P.

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Sequential hydroformylation aldol addition reactions of beta,gamma-unsaturated ketones and their derivatives

机译：β，γ-不饱和酮及其衍生物的顺序加氢甲酰化羟醛加成反应

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Novel rhodium(I) complex catalysed tandem hydroformylation/aldol reactions of a beta,gamma-unsaturated ketone 1 or its silyl enol ethers 4 in a one-pot procedure are presented to give varying cyclisation products depending on the reaction conditions. (C) 1999 Elsevier Science Ltd. All rights reserved. [References: 25]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |1999年第23期| 共4页
作者
Hollmann C.; Eilbracht P.;
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正文语种 eng
中图分类有机化学 ;
关键词
Aldol reactions; Amines; Hydroformylation; Rhodium catalysis; One-pot synthesis; Tertiary-amines; Rhodium; Olefins; Di(mu-chloro)bis(eta(4)-1; 5-cyclooctadiene)dirhodium; Alkylation; Secondary; Ammonia; Alpha;

机译：醛醇缩合反应;胺;加氢甲酰化;铑催化;一锅合成;叔胺;铑;烯烃;二（间氯）双（η（4）-1;5-环辛二烯）二ho;烷基化;二次;氨;Α;

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1. Sequential hydroformylation aldol addition reactions of beta,gamma-unsaturated ketones and their derivatives [J] . Hollmann C., Eilbracht P. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999 ,第23期

机译：β，γ-不饱和酮及其衍生物的顺序加氢甲酰化羟醛加成反应
2. Synthesis of beta-amino and beta-methoxy ketones by Lewis acids promoted beta-substitution reactions of beta,gamma-unsaturated ketones [J] . Lee ASY., Wang SH., Chang YT., Synlett . 2003 ,第15期

机译：路易斯酸合成β-氨基和β-甲氧基酮促进了β，γ-不饱和酮的β-取代反应
3. Sequential aldol Condensation-Transition metal-Catalyzed addition reactions of aldehydes, methyl ketones, and arylboronic acids [J] . Liao Y.-X., Xing C.-H., Israel M., Organic letters . 2011 ,第8期

机译：醛，甲基酮和芳基硼酸的顺序羟醛缩合过渡金属催化的加成反应
4. Ruthenium Hydride-Catalyzed Regioselective Addition of Aldehydes to Dienes Leading to beta,gamma-Unsaturated Ketones [C] . Sohei Omura, Takahide Fukuyama, Jiro Honguchi Symposium on Organometallic Chemistry . 2007

机译：钌氢化物催化的区域选择醛与导致β，γ-不饱和酮的二烯
5. I. Catalytic redox-initiated glycolate aldol additions of silyl glyoxylates. II. Diastereoselective de novo synthesis of pentasubstituted γ-butyrolactones from silyl glyoxylates and ketones via double Reformatsky reactions. III. Progress toward the total synthesis of leustroducsin B [D] . Greszler, Stephen Nathaniel 2010

机译：I.甲硅烷基乙醛酸酯的催化氧化还原引发的乙醇酸酯醛醇加成物。二。通过双重Reformatsky反应从甲硅烷基乙醛酸酯和酮进行非对映选择性从头合成五取代的γ-丁内酯。三，全合成杜鹃花素B的研究进展
6. Sequential Aldol Condensation – Transition Metal-Catalyzed Addition Reactions of Aldehydes Methyl Ketones and Arylboronic Acids [O] . Yuan-Xi Liao, Chun-Hui Xing, Matthew Israel, -1

机译：连续羟醛缩合 - 醛的过渡金属催化的加成反应与甲基酮芳基硼酸
7. Synthesis of bicyclic compounds using sequential hydroformylation and aldol condensation of cyclic ketones with unsaturated side chains [O] . Scognamillo Sergio 2004

机译：顺序加氢甲酰化和带有不饱和侧链的环状酮的醛醇缩合合成双环化合物

Sequential hydroformylation aldol addition reactions of beta,gamma-unsaturated ketones and their derivatives

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