Cycloadditions of allylsilanes - Part 14. Enantiospecific synthesis of bicyclo[4.3.0]nonanes by asymmetric [3+2] cycloaddition of chiral allylsilanes

Knolker HJ.; Schmitt O.; Foitzik N.

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Cycloadditions of allylsilanes - Part 14. Enantiospecific synthesis of bicyclo[4.3.0]nonanes by asymmetric [3+2] cycloaddition of chiral allylsilanes

机译：烯丙基硅烷的环加成反应-第14部分。通过手性烯丙基硅烷的不对称[3 + 2]环加成反应合成双环[4.3.0]壬烷

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The titanium tetrachloride promoted [3+2] cycloaddition of (R)-(1-phenylprop-2-enyl)trimethylsilane (R)-4 (82% ee) and 1-acetylcyclohexene 1 provides an enantiospecific route to the bicyclo[4.3.0]nonane(+)-6. (C) 1999 Elsevier Science Ltd. All rights reserved. [References: 35]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |1999年第18期| 共4页
作者
Knolker HJ.; Schmitt O.; Foitzik N.;
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正文语种 eng
中图分类有机化学 ;
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Optically-active allylsilanes; Carbon-silicon bond; Transition-metal complexes; Stereoselective synthesis; Organic-synthesis; Conjugate addition; Oxidative cleavage; Annulation; Hydroxycyclopentanes; lt; 3+2gt; cycloaddition;

机译：旋光烯丙基硅烷;碳硅键;过渡金属配合物;立体选择性合成;有机合成;共轭加成;氧化裂解;环化;羟基环戊烷;3 + 2环加成;

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1. Cycloadditions of allylsilanes - Part 14. Enantiospecific synthesis of bicyclo[4.3.0]nonanes by asymmetric [3+2] cycloaddition of chiral allylsilanes [J] . Knolker HJ., Schmitt O., Foitzik N. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999 ,第18期

机译：烯丙基硅烷的环加成反应-第14部分。通过手性烯丙基硅烷的不对称[3 + 2]环加成反应合成双环[4.3.0]壬烷
2. STEREOSELECTIVE SYNTHESIS OF TETRAHYDROFURAN BY DIASTEROSELECTIVE [3+2] CYCLOADDITION REACTION OF CHIRAL ALLYLSILANE WITH alpha-KETO ESTER [J] . Takahiko Akiyama, Shinya Funaki, Kohei Fuchibe Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2006 ,第1期

机译：手性烯丙基硅烷与α-酮基酯的对映选择性[3 + 2]环化反应立体合成四氢呋喃
3. A reinvestigation of the reaction of allylsilanes with N-phenyltriazolinedione:stereoselective synthesis of substituted urazoles by [3+2] cycloaddition [J] . Raudra T.Dey, Sk.Anwarul Haque, Anindya Hazra Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007 ,第38期

机译：烯丙基硅烷与N-苯基三唑啉二酮的反应的再研究：通过[3 + 2]环加成反应立体合成取代的脲唑
4. Enantioselective 3+2 Cycloaddition Reaction of 1-Alkylallenylsilane with alpha-Imino Ester: Chiral Synthesis of Pyrroline Derivatives [C] . Kazunori Daidouji, Kohei Fuchibe, Takahiko Akiyama Symposium on Organometallic Chemistry . 2004

机译：1-烷基铝基硅烷与α-亚氨基酯的映选择性3 + 2环加成反应：吡咯啉衍生物的手性合成
5. Asymmetric intramolecular Diels-Alder cycloadditions of 2-pyrone carboxylates and application toward an enantiospecific total synthesis of 1-beta, 25-dihydroxy, 2-beta-butylvitamin D(3). Development of novel inducers of anticarcinogenic detoxication enzymes: Design and synthesis of bifunctional isothiocyanate analogs of sulforaphane [D] . Cho, Cheon-Gyu 1994

机译：2-吡喃酮羧酸酯的不对称分子内Diels-Alder环加成反应及其对1-β，25-二羟基，2-β-丁基维生素D（3）的对映体特异性合成的应用。新型抗癌脱毒酶诱导剂的开发：萝卜硫烷双功能异硫氰酸酯类似物的设计和合成
6. Synthesis of (+)-Bullatacin via the Highly Diastereoselective 3+2 Annulation Reaction of a Racemic Aldehyde and a Non-Racemic Allylsilane [O] . Jennifer M. Tinsley, Eric Mertz, Pek Y. Chong, -1

机译：外消旋醛与非外消旋烯丙基硅烷的高度非对映选择性3 + 2环合反应合成（+）-布拉他星
7. Chiral iminoesters derived from d-glyceraldehyde in 3+2 cycloaddition reactions. Asymmetric synthesis of a key intermediate in the synthesis of neuramidinase inhibitors [O] . Gálvez José A., Díaz de Villegas María D., Alías Miriam, 2015

机译：在3 + 2环加成反应中衍生自d-甘油醛的手性亚氨基酯。神经酰胺酶抑制剂合成中关键中间体的不对称合成

Cycloadditions of allylsilanes - Part 14. Enantiospecific synthesis of bicyclo[4.3.0]nonanes by asymmetric [3+2] cycloaddition of chiral allylsilanes

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