USE OF REDUCTIVE PROPERTIES OF IODOTRICHLOROSILANE .2. CHEMOSELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES

Elmorsy SS.; Soliman H.; Amer FA.; Eiahl AAS.

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USE OF REDUCTIVE PROPERTIES OF IODOTRICHLOROSILANE .2. CHEMOSELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES

机译：使用碘代富三氯硅烷的还原性能.2。化学选择性还原α，不饱和酮和丁腈

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A new synthetic procedure for the selective reduction of alpha,beta-unsaturated ketones and nitriles, using iodotrichlorosilane (ITCS generated in situ from SiCl4-Nal) under mild conditions to produce the corresponding saturated ketone and nitrile compounds in quantitative yields, is described. [References: 9]

机译：描述了一种新的合成方法，用于选择性还原α，β-不饱和酮和腈，该方法使用碘代三氯硅烷（ITCS由SiCl4-Nal原位生成）在温和条件下以定量收率生产相应的饱和酮和腈化合物。 [参考：9]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1996年第13期|共2页
作者
Elmorsy SS.; Soliman H.; Amer FA.; Eiahl AAS.;
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正文语种 eng
中图分类有机化学;
关键词
Carbonyl-compounds; Secondary amides;

机译：羰基化合物;仲酰胺;

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专利

1. USE OF REDUCTIVE PROPERTIES OF IODOTRICHLOROSILANE .2. CHEMOSELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES [J] . Elmorsy SS., Soliman H., Amer FA., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第13期

机译：使用碘代富三氯硅烷的还原性能.2。化学选择性还原α，不饱和酮和丁腈
2. Chemoselective and metal-free reduction of alpha,beta-unsaturated ketones byin situproduced benzeneselenol fromO-(tert-butyl) Se-phenyl selenocarbonate [J] . Temperini Andrea, Ballarotto Marco, Siciliano Carlo RSC Advances . 2020,第56期

机译：alpha，β-不饱和酮的化学选择性和无金属化合物通过原位苯并苯甲烯醇（叔丁基）Se-苯基硒碳酸酯
3. Chemoselective Luche-Type Reduction of alpha,beta-Unsaturated Ketones by Magnesium Catalysis [J] . Jang Yoon Kyung, Magre Marc, Rueping Magnus Organic letters . 2019,第20期

机译：通过镁催化，ChemosElcentive Luche型α，β不饱和酮的减少
4. Catalytic 1,4-Reduction of alpha,beta-Unsaturated Ketones and Application to Asymmetric Synthesis of Warfarin [C] . Yasunori Tsuchiya, Ken-ichi Moriya, Christine Beemelmanns Symposium on Organometallic Chemistry . 2006

机译：催化1,4-减少α，β-不饱和酮和施用于Warfarin的不对称合成
5. I. Chemoselective catalytic hydrogenation of alpha, beta-unsaturated aldehydes and ketones using soluble copper(I) hydrides II. Free radical alkylation of titanium(III) allyl and propargyl complexes. [D] . Chen, Jianxian. 1999

机译：I.使用可溶的氢化铜（I）对α，β-不饱和醛和酮进行化学选择性催化氢化。钛（III）烯丙基和炔丙基复合物的自由基烷基化。
6. Chemoselective reduction and oxidation of ketones in water through control of the electron transfer pathway [O] . Sun Min Kim, Ho Sung Yoo, Hideo Hosono, -1

机译：通过控制电子传递途径对水中的酮进行化学选择性还原和氧化
7. Synthesis of beta-phenylchalcogeno-alpha, beta-unsaturated esters, ketones and nitriles using microwave and solvent-free conditions [O] . Eder J. Lenardão, Márcio S. Silva, Samuel R. Mendes, 2007

机译：使用微波和无溶剂条件合成β-苯基晶丙基霉素-α，β-不饱和酯，酮和腈

USE OF REDUCTIVE PROPERTIES OF IODOTRICHLOROSILANE .2. CHEMOSELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES

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