NONCONJUGATED DIENES FROM 1-ALKENES - APPLICATION TO THE SYNTHESIS OF SEX PHEROMONE (4E,7Z)-4,7-TRIDECADIENYL ACETATE

Kim TH.; Park KM.

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NONCONJUGATED DIENES FROM 1-ALKENES - APPLICATION TO THE SYNTHESIS OF SEX PHEROMONE (4E,7Z)-4,7-TRIDECADIENYL ACETATE

机译：1-烯烃的非共轭二烯-在合成性信息素（4E，7Z）-4,7-三癸二乙酸酯中的应用

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(4E,7Z)-4,7-Tridecadienyl acetate 1, a component of the sex pheromone was synthesized from 5-hexenyl acetate. (E)-gamma,delta-Unsaturated phosphonate as the key intermediate afforded a target molecule, using the Homer-Wadsworth-Emmons (HWE) reaction and desulfonylation as the main process. [References: 27]

机译：（4E，7Z）-4，7-十三碳二烯基乙酸酯1是由5-己烯基乙酸酯合成的性信息素的成分。（E）-γ，δ-不饱和膦酸酯为主要中间体，使用荷马-沃兹沃思-埃蒙斯（HWE）反应和脱磺酰作用为主要过程，从而提供了目标分子。 [参考：27]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第27期|共4页
作者
Kim TH.; Park KM.;
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正文语种 eng
中图分类有机化学;
关键词
Potato tuberworm moth; Phthorimaea-operculella; Insect pheromones; Sulfones; Zeller;

机译：马铃薯块茎蛾;小菜蛾;昆虫信息素;砜;泽勒;

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1. NONCONJUGATED DIENES FROM 1-ALKENES - APPLICATION TO THE SYNTHESIS OF SEX PHEROMONE (4E,7Z)-4,7-TRIDECADIENYL ACETATE [J] . Kim TH., Park KM. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第27期

机译：1-烯烃的非共轭二烯-在合成性信息素（4E，7Z）-4,7-三癸二乙酸酯中的应用
2. EXO- AND ENDOHORMONES XXI: STEREOSELECTIVE SYNTHESIS OF THE FOUR ISOMERS OF THE 4,7-TRIDECADIEN-1-YL ACETATE. (4E,7Z)-4,7-TRIDECADIEN-1-YL ACETATE, THE SEX PHEROMONE OF THE LEAFMINER MOTH PHYLONORYCTER CORYLIFOLIELLA [J] . Lucia GANSCA, Alexandra GOCAN, Ioan OPREAN, Revue roumaine de chimie . 2001,第11期

机译：内外泌体XXI：乙酸4,7-三癸基-1-基酯的四个异构体的立体选择性合成。（4E，7Z）-4,7-TRIDECADIEN-1-YL乙酸盐，叶蛾类植物性信息素的性信息素
3. STEREOSELECTIVE SYNTHESIS OF 1,4-DIENES - APPLICATION TO THE PREPARATION OF INSECT PHEROMONES (3Z,6Z)-DODECA-3,6-DIEN-1-OL AND (4E,7Z)-TRIDECA-4,7-DIENYL ACETATE [J] . Hutzinger MW., Oehlschlager AC. The Journal of Organic Chemistry . 1995,第14期

机译：1,4-二烯的立体选择性合成-在制备昆虫信息素（3Z，6Z）-DODECA-3,6-DIEN-1-OL和（4E，7Z）-TRIDECA-4,7-乙酸二乙酯中的应用
4. One-step synthesis of substituted 4,7-bisalkyl(aryl)imino-3-oxa-6-thia-1, azaspiro 4.4 nona-1,8-dienes [C] . Hoorieh Djahaniani, Issa Yavari European Symposium on Organic Chemistry . 2009

机译：取代的4,7-双烷基（芳基）咪尼 -3-牛氨基 -3-Oxa-6-Thia-1，Azaspiro 4.4非A-1,8-二烯的一步合成
5. Fluorous Mitsunobu reactions and total synthesis of sixteen stereoisomers of pine sawfly sex pheromone by fluorous mixture synthesis. [D] . Dandapani, Sivaraman. 2004

机译：氟Mitsunobu反应和通过氟混合物合成全合成16种松树蝇性信息素立体异构体。
6. Synthesis of Ultrahigh Molecular Weight Polymers Containing Reactive Functionality with Low PDIs by Polymerizations of Long-Chain α-Olefins in the Presence of Their Nonconjugated Dienes by Cp*TiMe2(O-26-iPr2C6H3)–Borate Catalyst [O] . Kotohiro Nomura, Sarntamon Pengoubol, Wannida Apisuk 2020

机译：Cp * TiMe2（O-26-iPr2C6H3）-硼酸盐催化剂在长链α-烯烃非共轭二烯存在下的聚合反应合成具有低PDI活性的超高分子量聚合物
7. Pheromone synthesis. XXII. A new synthesis of a stereoisomeric mixture of 3,7-dimethylpentadec-2-yl acetate, the sex pheromone of the pine sawflies. [O] . Kenji MORI, Satoru MASUDA, Masanao MATSUI 1978

机译：信息素合成。 XXII。一种新的3,7-二甲基戊二烷基-2-基醋酸酯的立体异构混合物的新合成，松树锯花的性信息素。

NONCONJUGATED DIENES FROM 1-ALKENES - APPLICATION TO THE SYNTHESIS OF SEX PHEROMONE (4E,7Z)-4,7-TRIDECADIENYL ACETATE

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