ASYMMETRIC ALLYLATION REACTIONS OF ACHIRAL ALDEHYDES WITH DIALLYLTIN DIBROMIDE BY THE USE OF CHIRAL DIAMINES

Kobayashi S.; Nishio K.

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ASYMMETRIC ALLYLATION REACTIONS OF ACHIRAL ALDEHYDES WITH DIALLYLTIN DIBROMIDE BY THE USE OF CHIRAL DIAMINES

机译：手性二胺类化合物与二烯丙基二溴化手性醛的不对称烷基化反应

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摘要

Asymmetric allylation reactions of achiral aldehydes with diallyltin dibromide have been achieved by using a chiral diamine derived from L-proline as a promoter. [References: 18]

机译：通过使用衍生自L-脯氨酸的手性二胺作为促进剂，已经实现了非手性醛与二烯丙基二溴化物的不对称烯丙基化反应。 [参考：18]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第37期|共4页
作者
Kobayashi S.; Nishio K.;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Enantioselective synthesis; Homoallyl alcohols; Facile; Ethers;

机译：对映选择性合成;烯丙基醇;易制;醚;

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1. ASYMMETRIC ALLYLATION REACTIONS OF ACHIRAL ALDEHYDES WITH DIALLYLTIN DIBROMIDE BY THE USE OF CHIRAL DIAMINES [J] . Kobayashi S., Nishio K. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第37期

机译：手性二胺类化合物与二烯丙基二溴化手性醛的不对称烷基化反应
2. Asymmetric α-allylation of α-branched aldehydes with allyl alcohols by synergistic catalysis using an achiral palladium complex and a chiral primary amino acid [J] . YoshidaM., MasakiE., TerumineT., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2014,第10期

机译：通过使用甲状腺钯络合物和手性原发性氨基酸通过协同催化催化催化与烯丙基醇的不对称α-烯丙基α-烯丙基
3. Direct asymmetric α-allylation of α-branched aldehydes by two catalytic systems with an achiral Pd complex and a chiral primary α-amino acid [J] . Yoshida M., Terumine T., Masaki E., The Journal of Organic Chemistry . 2013,第21期

机译：通过两个具有非手性钯配合物和手性伯氨基酸的催化体系使α-支链醛类直接不对称α-烯丙基化
4. Organophotoredox and Chiral Chromium Hybrid Catalysis for Catalytic Asymmetric Allylation of Aldehydes with Unactivated Alkenes [C] . Harunobu Mitsunuma, Shun Tanabe, Hiromu Fuse 日本化学会春季年会講演予稿集 . 2018

机译：有机虫〜ox和手性铬杂交催化催化醛催化醛与未激活的烯烃
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp3)–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis [O] . Harunobu Mitsunuma, Shun Tanabe, Hiromu Fuse, 2019

机译：通过有机光氧化还原和手性铬杂化催化介导的烯丙基C（sp3）–H官能化催化醛与烯烃的不对称烯丙基化
7. Counterion-Enhanced Pd/Enamine Catalysis: Direct Asymmetric α-Allylation of Aldehydes with Allylic Alcohols by Chiral Amines and Achiral or Racemic Phosphoric Acids [O] . Ádám Márk Pálvölgyi, Jakob Smith, Michael Schnürch, 2020

机译：抗衡离子型Pd /烯氨氨酸催化：通过手性胺和成立或外消旋磷酸直接与烯丙基醇的醛的非对称α-烯丙胺

ASYMMETRIC ALLYLATION REACTIONS OF ACHIRAL ALDEHYDES WITH DIALLYLTIN DIBROMIDE BY THE USE OF CHIRAL DIAMINES

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