HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS ACIDS

Dussault PH.; Zope U.

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HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS ACIDS

机译：过氧化氢介导的C-C键形成-在路易斯酸存在下由烷氧过氧化物合成1,2-二氧戊环

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Lewis-acid activation of ozonolysis-derived hydroperoxyketals affords intermediate hydroperoxycarbenium ions (protonated carbonyl oxides) which undergo addition of allyltrimethylsilane to directly afford 1,2-dioxolanes. [References: 18]

机译：臭氧分解衍生的氢过氧缩酮的路易斯酸活化得到中间体氢过氧碳鎓离子（质子化的羰基氧化物），其经过添加烯丙基三甲基硅烷以直接得到1，2-二氧戊环。 [参考：18]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |1995年第21期| 共4页
作者
Dussault PH.; Zope U.;
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正文语种 eng
中图分类有机化学 ;
关键词
Unsaturated hydroperoxides; Cyclic peroxides; Carbonyl oxides;

机译：不饱和氢过氧化物;环过氧化物;氧化碳;

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1. HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS ACIDS [J] . Dussault PH., Zope U. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995 ,第21期

机译：过氧化氢介导的C-C键形成-在路易斯酸存在下由烷氧过氧化物合成1,2-二氧戊环
2. A Facile, Superacid-Promoted Sequential Domino One-Pot Dual C-C Bond Formation and Fischer Indole Synthesis: Rapid Access to 10-Phenyl-5,10-dihydroindeno[1,2-b]indoles [J] . Reddy Alavala Gopi Krishna, Satyanarayana Gedu Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2015 ,第9期

机译：容易，超酸促进的顺序Domino单一锅双C-C键合形成和Fischer Indole合成：快速进入10-苯基-5,10-二氢茚[1,2-B]吲哚
3. Selectivity in Lewis acid-mediated fragmentations of peroxides and ozonides: application to the synthesis of alkenes, homoallyl ethers, and 1,2-dioxolanes [J] . Dussault PH., Liu XJ., Lee HJ. Journal of the Chemical Society, Perkin Transactions 1 . 2000 ,第17期

机译：在路易斯酸介导的过氧化物和臭氧化物片段化中的选择性：在烯烃，高烯丙基醚和1,2-二氧戊环的合成中的应用
4. Oxidative Intramolecular Multiple C-C Bonds Formation Reactionsof 1,2-Diarylbenzens [C] . Islam Md.Rafikul, Ken-ichi Sugiura 日本化学会春季年会 . 2020

机译：氧化分子内多C-C键形成反应1,2-二芳基苯
5. Cyclic Peroxide Methodologies: I. Synthesis of 10,12-Peroxycalamenene Using an SN1-type Reaction to Construct the 1,2-Dioxepane Ring. II. Cobalt-Catalyzed C-Br Bond Activation to Form 1,2-Dioxolanes [D] . Witthoft, Luke. 2018

机译：环状过氧化物方法：I.使用SN1型反应合成10,12-过氧哒甘油，以构建1,2-二氧己烯环。 II。钴催化的C-Br键活化以形成1,2-二氧戊烷
6. Transition-metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction [O] . Sarbani Pal, Mohammad Ashrafuddin Khan, P Bindu, 2007

机译：通过C-C键形成反应的过渡金属/路易斯酸无规合成酰基苯并噻吩
7. Transition-metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction [O] . Pal, Sarbani, Khan, Mohammad Ashrafuddin, Bindu, P, 2007

机译：通过C-C键形成反应的过渡金属/路易斯酸无规合成酰基苯并噻吩

HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS ACIDS

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