Synthesis and characterization of flavin-tethered peptide nucleic acid

Hisafumi Ikeda; Kohzo Yoshida; Makoto Ozeki; Isao Saito

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Synthesis and characterization of flavin-tethered peptide nucleic acid

机译：黄素束缚肽核酸的合成与表征

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We synthesized flavin-containing PNA monomer unit 5 from lumiflavin and prepared PNAs containing a flavin moeity (FPNA) by the standard tBoc chemistry. Each PNA oligomer was purified by reversed-phase HPLC and characterized by MALDI-TOF MS and UV spectra. Thermodynamic analyses indicated that the PNA oligomer containing a flavin moiety near the amino terminal considerably stabilized the PNA-DNA hybrids.

机译：我们从lumiflavin合成了含黄素的PNA单体单元5，并通过标准tBoc化学方法制备了含有黄素部分（FPNA）的PNA。每个PNA低聚物均通过反相HPLC纯化，并通过MALDI-TOF MS和UV光谱进行表征。热力学分析表明，在氨基末端附近含有黄素部分的PNA低聚物大大稳定了PNA-DNA杂化物。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2001年第13期|共3页
作者
Hisafumi Ikeda; Kohzo Yoshida; Makoto Ozeki; Isao Saito;
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中图分类有机化学;
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1. Synthesis and characterization of flavin-tethered peptide nucleic acid [J] . Hisafumi Ikeda, Kohzo Yoshida, Makoto Ozeki, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第13期

机译：黄素束缚肽核酸的合成与表征
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Synthesis and characterization of flavin-tethered peptide nucleic acid

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