Tetrakis(dimethlamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates. A new simple access to heteroaryl-SCF_2R derivatives

Theirry Billard; Bernard R.Langlois; Maurice Medebielle

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Tetrakis(dimethlamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates. A new simple access to heteroaryl-SCF_2R derivatives

机译：四（二甲基氨基）乙烯（TDAE）介导将二氟甲基阴离子添加到杂芳基硫氰酸酯中。杂芳基-SCF_2R衍生物的新的简单访问

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New heteroaryl-SCF_2R derivatives 8-13 are easily obtained in one-pot from the tetrakis(dimethylamino)ethylene (TDAE_ mediated reduction of halogenodifluoromethyl substrates RCF_2X 1-4 in the presence of heteroaryl-thiocyanates 5-7.

机译：在杂芳基-硫氰酸酯5-7存在下，容易地从四（二甲基氨基）乙烯（TDAE_介导的卤代二氟甲基底物RCF_2X 1-4的还原）一锅中容易地获得新的杂芳基-SCF_2R衍生物8-13。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2001年第20期|共3页
作者
Theirry Billard; Bernard R.Langlois; Maurice Medebielle;
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1. Tetrakis(dimethlamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates. A new simple access to heteroaryl-SCF_2R derivatives [J] . Theirry Billard, Bernard R.Langlois, Maurice Medebielle Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第20期

机译：四（二甲基氨基）乙烯（TDAE）介导将二氟甲基阴离子添加到杂芳基硫氰酸酯中。杂芳基-SCF_2R衍生物的新的简单访问
2. Tetrakis(dimethylamino)ethylene (TDAE) mediated addition of heterocyclic difluoromethyl anions to heteroaryl aldehydes. A facile synthetic method for new gem-difluorinated alcohols derived from 4-bromo-1-naphthylamine and 8-quinolylamine [J] . Medebielle M., Okada E., Ashida T., Synlett . 2001,第6期

机译：四（二甲基氨基）乙烯（TDAE）介导的杂环二氟甲基阴离子加成到杂芳基醛上。一种简便的合成方法，用于从4-溴-1-萘胺和8-喹啉胺衍生的新的宝石二氟化醇
3. Tetrakis(dimethylamino)ethylene (TDAE) mediated addition of heterocyclic difluoromethyl anions to heteroaryl aldehydes. A facile synthetic method for new gem-difluorinated alcohols derived from 4-bromo-1-naphthylamine and 8-quinolylamine [J] . Medebielle M., Okada E., Ashida T., Synlett . 2001,第6期

机译：四（二甲基氨基）乙烯（TDAE）介导的杂环二氟甲基阴离子加成到杂芳基醛上。一种简便的合成方法，用于从4-溴-1-萘胺和8-喹啉胺衍生的新的宝石二氟化醇
4. Carbon-Carbon Bond Formation Using Tetrakis(dimethylamino)-ethylene (TDAE) as Reductant/Mediator [C] . Manabu KUROBOSHI, Suguru KISHIMOTO, Kentaro GOTO, Fourth International Manuel M. Baizer Symposium, 2000 . 2000

机译：使用四（二甲基氨基）-乙烯（TDAE）作为还原剂/介体的碳-碳键形成
5. Novel Synthesis of Azepine Derivatives via Copper-Mediated Cyclization of 2-Aza-hepta-2, 4-dien-6-ynyl Anions. Intramolecular Addition of Organocopper Centers to the C-C Triple Bond [O] . -1

机译：通过铜介导的2-烷庚基-2，4-DIEN-6-炔灭绝的致铜介导环化的新颖合成。对C-C三键的分子内加入有机缺乏症

Tetrakis(dimethlamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates. A new simple access to heteroaryl-SCF_2R derivatives

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