An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions

Kiyooka Syun-ichi

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An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions

机译：基于手性草氮杂硼硼烷酮促进的不对称醛醇缩合反应，多烯大环内酯类抗生素菲律宾蛋白III中多乙酸酯链的有效延伸

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The enantioselective construction of the iterative polyacetate unit 3 in filipin III has been accomplished, essentially by an aldol strategy based on chiral ooxazaborolidinone-promoted asymmetric aldol reactions.

机译：基本上通过基于手性oxazaborolidinone促进的不对称羟醛反应的羟醛策略，完成了在菲林III中的迭代多乙酸酯单元3的对映选择性构建。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2000年第39期|共6页
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Kiyooka Syun-ichi;
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正文语种 eng
中图分类有机化学;
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1. An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions [J] . Kiyooka Syun-ichi Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第39期

机译：基于手性草氮杂硼硼烷酮促进的不对称醛醇缩合反应，多烯大环内酯类抗生素菲律宾蛋白III中多乙酸酯链的有效延伸
2. A practical synthesis of essentially enantiopure syn-propionate aldols using a chiral oxazaborolidinone-promoted asymmetric aldol reaction coupled with radical reduction [J] . Kiyooka S., Hena MA., Shahid KA. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第35期

机译：使用手性草并氮杂硼硼烷酮促进的不对称醛醇缩合反应与自由基还原反应，实际合成基本上对映纯的丙酸醛缩醇
3. Efficient enantio- and diastereoselective synthesis of enantiopure syn-alpha-bromo-beta-hydroxy-alpha-methylpropionate esters and their-cis-alpha,beta-epoxy derivatives based on a chiral oxazaborolidinone-promoted asymmetric aldol reaction [J] . Kiyooka S., Shahid DA. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2000,第7期

机译：基于手性草氮杂硼烷酮促进的不对称醛醇缩合反应的对映纯纯α-溴-β-羟基-α-甲基丙酸酯对映体和非对映异构体的高效合成
4. Asymmetric Direct Aldol Reaction with Chiral Rh(Phebox) Complexes [C] . Hiroko Inoue, Makoto Kikuchi, Hisao Nishiyama Symposium on Organometallic Chemistry . 2007

机译：不对称直接醛醇反应与手性RH（Phebox）复合物
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Fluorescence Studies of the Binding of the Polyene Antibiotics Filipin III Amphotericin B Nystatin and Lagosin to Cholesterol [O] . Robert Bittman, Steven A. Fischkoff 1972

机译：多烯抗生素菲律宾三两性霉素B制霉菌素和拉各斯汀与胆固醇结合的荧光研究
7. Solution NMR structures of the polyene macrolide antibiotic filipin III11Web site available at http://sakura.cpe.fr [O] . Volpon Laurent, Lancelin Jean-Marc 2000

机译：多烯大环内酯抗生素菲律宾蛋白III11网站的溶液NMR结构可从http://sakura.cpe.fr获得

An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions

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