Aza-Diels-Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

Chou Shang-Shing P.

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Aza-Diels-Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

机译：硫取代的1,3-二烯与芳基磺酰基异氰酸酯的Aza-Diels-Alder反应和合成应用

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摘要

The first aza-Diels-Alder reactions of arylsulfonyl isocyanates with thio-substituted 1,3-dienes via the 3-sulfolene precursors 1 gave the cyclized products 3 with complete control of regio-and chemoselectivity. The cyclized products 3a and 4 underwent further interesting reactions with nucleophiles and bases to give useful heterocyclic compounds.

机译：芳基磺酰基异氰酸酯与硫代取代的1，3-二烯经3-环丁烯前体1的第一次氮杂-狄尔斯-阿尔德反应产生了完全控制区域和化学选择性的环化产物3。环化产物3a和4与亲核试剂和碱进行进一步有趣的反应，得到有用的杂环化合物。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2000年第43期|共4页
作者
Chou Shang-Shing P.;
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正文语种 eng
中图分类有机化学;
关键词
aza-Diels-Alder reactions; 1; 3-dienes; arylsulfonyl isoocyanate;

机译：aza-Diels-Alder反应;1;3-二烯;芳基磺酰基异氰酸酯;

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1. Aza-Diels-Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates [J] . Chou Shang-Shing P. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第43期

机译：硫取代的1,3-二烯与芳基磺酰基异氰酸酯的Aza-Diels-Alder反应和合成应用
2. Synthesis of pipecolic acid derivatives via AZA-diels-alder reactions of thio-substituted 1,3-butadienes with iminium salts [J] . Shang-Shing P.Chou, Chia-Cheng Hung Synthetic Communications . 2002,第20期

机译：硫代取代的1,3-丁二烯与亚胺盐的AZA-diels-alder反应合成胡椒酸衍生物
3. Cycloaddition reactions of 2,4-diphenyl-1,3-diazabuta-1,3-dienes with isocyanates and isothiocyanates [J] . Abbiati G., de Carvalho AC., Rossi E. Tetrahedron . 2003,第37期

机译：2,4-二苯基-1,3-二氮杂丁-1,3-二烯与异氰酸酯和异硫氰酸酯的环加成反应
4. Imines derived from enantiopure trans-3-amino-azetidin-2-ones as dienophiles in aza-Diels-Alder reactions with activated and nonactivated dienes(Abstracts) [C] . Tanja Poljak, Kresimir Molcanov, Davor Margetic European Symposium on Organic Chemistry . 2007

机译：酰胺衍生自EnAliopure Trans-3-氨基 - azetidin-2-α-二氧化铝 - 桤木反应中的Diuenophiles，其与活化和非活化的二烯（摘要）
5. Synthesis of 2-boron substituted-1,3-dienes and their Diels-Alder/Suzuki cross coupling reactions. [D] . Wang, Liqiong. 2012

机译：2-硼取代的1,3-二烯的合成及其Diels-Alder / Suzuki交叉偶联反应。
6. Asymmetric aza-Diels-Alder reaction of Danishefskys diene with imines in a chiral reaction medium [O] . Bruce Pégot, Olivier Nguyen Van Buu, Didier Gori, 2006

机译：手性反应介质中丹尼舍夫斯基二烯与亚胺的不对称aza-Diels-Alder反应
7. Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications [O] . Luo Shao-Xiong, Cannon Jeffrey S., Taylor Buck L. H., 2016

机译：3E-1,3-二烯的Z选择性交叉复分解和均聚化：反应优化，计算分析和合成应用

Aza-Diels-Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

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