Synthesis of conformationally locked C-nucleosides having a 2,5-dioxabicyclo[2.2.1]heptane ring system

Obika Satoshi; Hari Yoshiyuki; Morio Ken-ichiro; Imanishi Takeshi

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Synthesis of conformationally locked C-nucleosides having a 2,5-dioxabicyclo[2.2.1]heptane ring system

机译：具有2,5-二氧杂双环[2.2.1]庚烷环系统的构象锁定的C-核苷的合成

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摘要

Some novel C-nucleosides having a 2,5-dioxabicyclo[2.2.1]heptane ring system were successfully synthesized via the coupling reactionof tetrahydrofurancarbaldehyde 1 with the lithium and the magnesium derivatives of aromatic heterocycles.

机译：通过四氢呋喃甲醛1与芳族杂环的锂和镁衍生物的偶联反应，成功合成了具有2,5-二氧杂双环[2.2.1]庚烷环系统的新型C-核苷。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2000年第2期|共5页
作者
Obika Satoshi; Hari Yoshiyuki; Morio Ken-ichiro; Imanishi Takeshi;
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正文语种 eng
中图分类有机化学;
关键词
nucleic acid analogues; bicyclic heterocyclic compounds; nitrogen heterocycles; Mitsunobu reactions;

机译：核酸类似物;双环杂环化合物;氮杂环;Mitsunobu反应;

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1. Synthesis of conformationally locked C-nucleosides having a 2,5-dioxabicyclo[2.2.1]heptane ring system [J] . Obika Satoshi, Hari Yoshiyuki, Morio Ken-ichiro, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第2期

机译：具有2,5-二氧杂双环[2.2.1]庚烷环系统的构象锁定的C-核苷的合成
2. SYNTHESIS OF NOVEL CONFORMATIONALLY LOCKED CARBOCYCLIC NUCLEOSIDES DERIVED FROM 3-(HYDROXYMETHYL)BICYCLO[2.2.1]HEPTANE-2,5-DIOL [J] . Hubert HREBABECKY, Milena MASOJIDKOVA, Martin DRACINSKY, Collection of Czechoslovak Chemical Communications . 2006,第6期

机译：3-（羟甲基）双环[2.2.1]庚烷-2,5-二醇衍生的新型构象完全锁定的碳环核苷的合成
3. Distal Two-Bond versus Three-Bond Electronegative Oxo-Substituent Effect Controls the Kinetics and Thermodynamics of the Conversion of a C?Nitroso Function to the Corresponding Oxime in the Conformationally Locked Pentofuranose (Bicyclo[2.2.1]heptane) System [J] . Mansoureh Karimiahmadabadi, Sayeh Erfan, Andras Fo?ldesi, The Journal of Organic Chemistry . 2014,第16期

机译：远端二键与三键电负性氧取代效应控制构象锁定戊呋喃糖（双环[2.2.1]庚烷）系统中C→亚硝基官能向相应肟转化的动力学和热力学。
4. 7-Azabicyclo2.2.1heptane-2-carboxylic acids as peptidomimetic conformational constraints. NK2 antagonists as an example [C] . Susan Northfield, Michelle Camerino, Hayley Mulvey International Peptide Symposium . 2009

机译：7-氮杂双环2.2.1庚烷-2-羧酸作为肽模拟构象约束。 NK2拮抗剂作为一个例子
5. REACTIVE INTERMEDIATES IN THE TRICYCLO(3.2.1.0(2,4)) OCTANE AND BICYCLO(2.2.1)HEPTANE RING SYSTEMS. [D] . POBER, KENNETH WILLIAM. 1968

机译：三环（3.2.1.0（2,4））辛烷和双环（2.2.1）庚烷环系统中的反应中间体。
6. Synthesis of a Novel Conformationally Locked Carbocyclic Nucleoside Ring System [O] . Hak Sung Kim, Kenneth A. Jacobson -1

机译：新型构象锁定碳环核苷环系统的合成
7. Chemospecific and diastereoselective synthesis of bis-dioxabicyclo[2.2.1]heptanone ring systems [O] . Sengodagounder Muthusamy, Janagiraman Krishnamurthi, Eringathodi Suresh 2004

机译：化学特异性和非对映选择性合成双 - 二氧杂双环[2.2.1]庚酮环系统
8. 2,3-Dioxabicyclo(2.2.1)Heptane. [R] . Porter, N. A., Gilmore, D. 1977

机译：2,3-二氧杂双环（2.2.1）庚烷。

Synthesis of conformationally locked C-nucleosides having a 2,5-dioxabicyclo[2.2.1]heptane ring system

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