Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes.

Bouyssi D.; Balme G.; Monteiro N.

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Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes.

机译：带有稳定亲核试剂的未活化炔烃的分子内碳青合反应：在合成环烯类萜烯中的应用。

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The copper-promoted cycloisomerization of unsaturated alkynes bearing a stabilized nucleophile is described, providing a novel synthesis of various iridoid monoterpenes. (C) 1999 Elsevier Science Ltd. All rights reserved. [References: 29]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1999年第7期|共4页
作者
Bouyssi D.; Balme G.; Monteiro N.;
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正文语种 eng
中图分类有机化学;
关键词
Alkynes; Cyclization; Vinyl copper; Iridoid monoterpenes; Epsilon-acetylenic esters; Carbonyl-compounds; Cyclization;

机译：炔烃;环化;乙烯基铜;环烯类萜烯;Epsilon-炔属酯;羰基化合物;环化;

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1. Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes. [J] . Bouyssi D., Balme G., Monteiro N. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第7期

机译：带有稳定亲核试剂的未活化炔烃的分子内碳青合反应：在合成环烯类萜烯中的应用。
2. Two Manifolds for Metal-Catalyzed Intramolecular Diels-Alder Reactions of Unactivated Alkynes [J] . Alois Fiirstner, Christopher C.Stimson Angewandte Chemie . 2007,第46期

机译：金属催化的未活化炔烃分子内Diels-Alder反应的两个流形
3. Stereoselective Synthesis of Polycycles Containing an Aziridine Group: Intramolecular aza-Diels-Alder Reactions of Unactivated 2H-Azirines with Unactivated Dienes [J] . Xu Hua-Dong, Zhou Hao, Pan Ying-Peng, Angewandte Chemie . 2016,第7期

机译：含氮丙啶基的多环化合物的立体选择性合成：未活化的2H-偶氮与未活化的二烯的分子内aza-Diels-Alder反应
4. Intramolecular Reactions of Alkynes with Alkenes Catalyzed by Platinum and Gold [C] . Antonio M. Echavarren, Cristina Nevado, Cristina Nieto-Oberhuber, NATO Advanced Study Institute on New Methodologies and Techniques for a Sustainable Organic Chemistry: Sustainable Development in a Secure Environment Certosa di Pontignano . 2008

机译：铂和金催化烯烃的分子内反应
5. Rhodium -catalyzed cyclization/hydrosilylation of diynes and enynes and transition metal -catalyzed addition of stabilized carbon nucleophiles to unactivated olefins and allenes [D] . Liu, Cong 2006

机译：铑催化的二炔和烯炔的环化/氢化硅烷化反应以及过渡金属催化的稳定碳亲核试剂向未活化的烯烃和丙二烯的加成
6. The enantioselective intramolecular aminative functionalization of unactivated alkenes dienes allenes and alkynes for the synthesis of chiral nitrogen heterocycles [O] . Sherry R. Chemler -1

机译：用于合成手性氮杂环的未活化烯烃二烯丙二烯和炔的对映选择性分子内胺化功能
7. Two Manifolds for Metal-Catalyzed Intramolecular Diels–Alder Reactions of Unactivated Alkynes [O] . Alois Fürstner, Christopher C. Stimson 2007

机译：用于金属催化的炔醇的金属催化分子分子间二氧化铝反应的两种歧管

Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes.

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