Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, gamma substituted, heteroatom-stabilized allyl cations in acidic polar media

Grieco PA.; Kaufman MD.

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Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, gamma substituted, heteroatom-stabilized allyl cations in acidic polar media

机译：通过酸性极性介质中原位生成的，γ取代的，杂原子稳定的烯丙基阳离子的分子内Diels-Alder反应进行官能化的碳环

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The synthesis of highly structured carbocyclic ring systems possessing quaternary carbon atoms has been realized via intramolecular Diels-Alder reactions of in situ-generated, gamma substituted, heteroatom-stabilized allyl cations in acidic polar media. (C) 1999 Elsevier Science Ltd. All rights reserved. [References: 6]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1999年第7期|共4页
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Grieco PA.; Kaufman MD.;
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中图分类有机化学;
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1. Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, gamma substituted, heteroatom-stabilized allyl cations in acidic polar media [J] . Grieco PA., Kaufman MD. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第7期

机译：通过酸性极性介质中原位生成的，γ取代的，杂原子稳定的烯丙基阳离子的分子内Diels-Alder反应进行官能化的碳环
2. Carbocyclic Ring Construction via Intramolecular Ionic Diels-Alder Reactions of in Situ-Generated, Heteroatom-Stabilized Allyl Cations in Highly Polar Media [J] . Paul A. Grieco, Michael D. Kaufman, John F. Daeuble, Journal of the American Chemical Society . 1996,第8期

机译：通过高极性介质中原位生成的，杂原子稳定的烯丙基阳离子的分子内离子Diels-Alder反应构建碳环
3. Carbocyclic Ring Construction via an Intramolecular Diels-Alder Reaction of an in Situ-Generated, Heteroatom-Stabilized Allyl Cation: Total Synthesis of (+-)-Lycopodine [J] . Alexey Rivkin, Dennis P. Curran Chemtracts . 1999,第4期

机译：通过原位生成的，杂原子稳定的烯丙基阳离子的分子内Diels-Alder反应构建碳环：（+-）-Lycopodine的全合成。
4. Allyl-based,C~(alpha)-methylated alpha-amino acids in the side-chain to side-chain ring-closing metathesis reaction of beta-turn/3_(10)-helical peptides [C] . Claudio Toniolo, Marco Crisma, Fernando Formaggio, the International Peptide Symposium . 2001

机译：基于烯丙基的C〜（α） - 侧链中的甲基化α-氨基酸与β转/ 3_（10） - 尿肽的侧链闭合复分解反应
5. 1. Studies directed toward the synthesis of 20B-carbachaparrinone analogs via a samarium (II) iodide ring closure of a highly functionalized intermediate. 2. Synthesis of 5-oxo-cyclopent-1-enecarboxylic acid methyl esters via a novel tandem aldol-knoevenagel condensation. 3. Novel carbocyclic ring formation via intramolecular enol trapping of an allyl cation in acidic polar media. [D] . DeSelms, Robert Herschel. 2002

机译：1.研究针对通过高度官能化中间体的碘化sa（II）闭环合成20B-氨基苯甲酰吗啉酮类似物。 2.通过新型串联的羟醛-knoevenagel缩合合成5-氧代-环戊-1-烯羧酸甲酯。 3.通过在酸性极性介质中烯丙基阳离子的分子内烯醇捕获而形成新的碳环。
6. Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes [O] . Laura S. Kocsis, Erica Benedetti, Kay M. Brummond 2013

机译：微波辅助分子内脱氢Diels-Alder反应合成功能化萘/溶剂变色染料
7. Diastereoselective intramolecular Diels-Alder reactions of masked o-benzoquinones: a short entry to highly functionalized tricyclic m.2.2.0 ring systems [O] . Chen YK 2011

机译：掩蔽的邻苯二醌的非对映选择性分子内Diels-Alder反应：进入高度官能化的三环m.2.2.0环系统的短暂时间

Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, gamma substituted, heteroatom-stabilized allyl cations in acidic polar media

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