A formal synthesis of (+/-) parvifoline by manganese(III)-based oxidative arylation of ketones

Bhowmik DR.; Venkateswaran RV.

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A formal synthesis of (+/-) parvifoline by manganese(III)-based oxidative arylation of ketones

机译：通过基于锰（III）的氧化芳基化反应正式合成（+/-）细小膦碱

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A short, formal synthesis of the phenolic sesquiterpene (+/-) parvifoline 1 is described involving manganese(III)based oxidative arylation of the ketone 9 as the key step. (C) 1999 Published by Elsevier Science Ltd. All rights reserved. [References: 11]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1999年第41期|共3页
作者
Bhowmik DR.; Venkateswaran RV.;
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正文语种 eng
中图分类有机化学;
关键词
Oxidative free-radical cyclization; Grob fragmentation; Benzocyclooctene; Free-radical cyclizations;

机译：氧化自由基环化;Grob断裂;苯并环辛烯;自由基环化;

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1. A formal synthesis of (+/-) parvifoline by manganese(III)-based oxidative arylation of ketones [J] . Bhowmik DR., Venkateswaran RV. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第41期

机译：通过基于锰（III）的氧化芳基化反应正式合成（+/-）细小膦碱
2. Manganese(III) acetate based oxidation of substitute alpha '-position on cyclic alpha,beta-unsaturated ketones [J] . Tanyeli C., Iyigun C. Tetrahedron . 2003,第36期

机译：基于乙酸锰（III）的环状α，β-不饱和酮上的替代α'-位的氧化
3. Manganese(III) acetate based tandem oxidation of various alpha and beta-alkoxy alpha,beta-unsaturated ketones [J] . Tanyeli C., Ozdemirhan D., Sezen B. Tetrahedron . 2002,第50期

机译：乙酸锰（III）串联氧化各种α和β-烷氧基α，β-不饱和酮
4. Synthesis and Characterization of Tetraphenylporphyrinate Manganese(III) Siloxides by Silyl Group Transfer from Silanethiols [C] . Zachary J. Tonzetich, Daniel J. Meininger, Zieph Kasrawi, ASMS Conference on Mass Spectrometry and Allied Topics . 2016

机译：硅烷硫醇甲硅烷基转移的四苯基晶锰（III）硅烷酯的合成与表征
5. Manganese(III)-based oxidative cyclizations: Formal synthesis of 15-acetoxypallescensin A. Synthesis of hindered guanidines. Completion of the total synthesis of martinellic acid. [D] . O'Hare, Sean Matthew. 2002

机译：基于锰（III）的氧化环化：15-乙酰氧基palscensin A的正式合成。受阻胍的合成。完成马汀酸的全合成。
6. Manganese(III)-Mediated Transformations of Phloroglucinols: A Formal Oxidative 4+2 Cycloaddition Leading to Bicyclo2.2.2octadiones [O] . Branko Mitasev, John A. Porco Jr -1

机译：锰（III）phloroglucinols的介导的转变：形式化氧化4 + 2环加成通向双环2.2.2 octadiones
7. Formal Synthesis of (±)-Allocolchicine Via Gold-Catalysed Direct Arylation: Implication of Aryl Iodine(III) Oxidant in Catalyst Deactivation Pathways [O] . Tom J. A. Corrie, Guy C. Lloyd-Jones 2017

机译：通过金催化直接芳基的正式合成（±） - oallocolchicine：芳基碘（III）氧化剂在催化剂失活途径中的含义
8. Carbon-Based Oxygen Electrodes for Metal-Air Batteries. III. The Carbon-Manganese Dioxide Electrode [R] . Armstrong, W. A. 1972

机译：用于金属空气电池的碳基氧电极。 III。碳 - 二氧化锰电极

A formal synthesis of (+/-) parvifoline by manganese(III)-based oxidative arylation of ketones

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